基于最佳温度和压力的新型低碳钢绿色防腐技术

S. Anbalagan, Ravisankar, R. Govindhan
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引用次数: 1

摘要

采用缩聚法制备了新型绿色催化剂1-[(4-硝基苯基)甲基]-4-(吡啶-2-基)哌嗪(NMPP)聚合物复合材料。采用傅里叶变换红外(FTIR)和高分辨率扫描电镜(HR-SEM)对聚合物复合材料进行了表征。采用常规失重法和电化学阻抗谱(EIS)研究了聚合物复合材料的缓蚀作用。在303 K下,浓度为6%时,缓蚀效率最高,为88.34%。结果表明,NMPP是一种混合型缓蚀剂,热力学和动力学参数也表明催化剂在温和表面上以放热方式吸附,并通过常规失重法证实了吸附作用。采用扫描电镜(HR-SEM)研究了低碳钢片的形貌。HR-SEM结果表明,新型催化剂对低碳钢在1 M HCL和CO2环境下的腐蚀有抑制作用。
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Novel Green Corrosion Protection for Mild Steel on Optimal Temperature and Pressure
The green novel catalyst 1-[(4-nitrophenyl) methyl]-4-(pyridin-2-yl)piperazine (NMPP) polymer composite was synthesized by condensation polymerization. The polymer composite was characterized by Fourier transform infrared (FTIR), and high resolution scanning electron microscope (HR-SEM). The inhibition action of the polymer composite was investigated by conventional weight loss method, and electrochemical impedance spectroscopy (EIS). The maximum corrosion inhibition efficiency of 88.34% was obtained at concentration level of 6% at 303 K. The results revealed NMPP as a mixed type corrosion inhibitor, the thermodynamic and kinetic parameters also revealed adsorption of catalyst on to mild surface as exothermic and the adsorption was confirmed by conventional weight loss method. The morphology of mild steel coupons was investigated by HR-SEM. The HR-SEM results showed novel catalyst to have inhibited corrosion on mild steel in 1 M HCL on CO2 environment.
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