利用“气味”检测塑料垃圾自燃

K. Kamiya, O. Sugawa, Tomohiko Imamura, Y. Oka
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引用次数: 3

摘要

堆积的塑料垃圾可能引起自燃。要注意到表明在堆积的材料中开始燃烧的微小迹象是极其困难的。利用温控炉模拟了塑料垃圾自燃过程,测量了自燃过程中试样的温度、产生的恶臭气体的强度和质量。将各种食品包装塑料组成的混合废塑料作为单个试样进行加热炉试验。测量了该样品和每个单独塑料产生的气味。结果表明,在点火过程中,由于材料中部的积热,相似指数醛/氨的比值增大。用TG-DTA法在常压条件下对单个塑料试样进行燃烧和热分解,其气味也表现出与混合试样相似的趋势。
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Detection of Spontaneous Combustion of Plastic Waste by “Odor”
Accumulated plastic waste is concerned to cause a spontaneous combustion. It is extremely difficult to notice the minor signs indicating the start of combustion inside the accumulated material. Spontaneous combustion of plastic waste was simulated using a temperature-controlled furnace, and the temperature of the sample and the intensity as well as quality of odorous gases emitted were measured during the process of self-ignition. Mixed plastic waste consisting of various plastics of food wrapping was subjected to heating furnace experiment as a single specimen. The odors generated from this specimen and each single individual plastic were measured. The ratio of the similarity indices aldehyde/ammonia was found to increase during the ignition process due to the accumulated heat in the central part of accumulated material. Specimens of individual plastic was burnt and thermally decomposed using TG-DTA under the normal atmospheric condition, the odor also showed a similar tendency with that obtained in the experiment for the mixed specimen.
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