堆肥材料去除废水中〖Cu〗^(2+)的动力学研究

M. Al-Alawi
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引用次数: 1

摘要

本研究的目的是利用连续固定床柱研究堆肥材料从不同参数的水溶液中去除{Cu}^{2+}的能力。利用傅里叶变换红外光谱对堆肥进行了表征,发现金属结合主要是金属阳离子与化学物质中羧基的离子相互作用。利用扫描电镜对吸附剂进行了形态分析,发现堆肥成分的变化可能与金属结合机制有关。金属加载前后的能量色散x射线能谱分析结果表明,复合材料对{Cu}^{2+}有吸附作用,金属参与了吸附过程中的相互作用。研究了初始{Cu}^{2+}浓度、流速、柱层高度、离子交换等因素对反应的影响。吸附动力学模型表明,{Cu}^{2+\}的吸附行为与浓度速率、流速和床层高度有关。
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Kinetics Study of The Ability of Compost Material for Removing 〖Cu〗^(2+) from Wastewater
The objective of this study is to examine the ability of a compost material for removing {Cu}^{2+} from aqueous solutions with different parameters using continuous fixed-bed column. Compost was characterized by using Fourier transform infrared spectroscopy which revealed that the metal binding is mainly contributed to the ionic interaction of the metal cations with the carboxyl groups in the hemic substances. Scanning electron microscope images were utilized for morphological analysis of the adsorbent and has revealed that the changes in compost composition could be related to the mechanism of metal binding. Energy dispersive X-ray spectroscopy was used before and after the metal had loaded and gives a good evidence on compost adsorption of {Cu}^{2+} and the metals have its involvement in the interaction in the adsorption process. The influence of the initial {Cu}^{2+}concentration, flow rate, bed heights of the column, and ion exchange have been studied in this research. The adsorption kinetic models have revealed that the behaviour of the {Cu}^{2+\ }adsorption is dependent on rate of concentration, flow rate, and bed heights.
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