染料敏化太阳能电池用金红石型TiO2的合成与沉积

Blen Teferi, U. Schnupf, Kazuhiro Manseki, T. Sugiura, S. Vafaei
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引用次数: 1

摘要

本研究的目的是利用纳米TiO2纳米颗粒,在掺f SnO2 (FTO)玻璃上,采用纳米流体沸腾法制备半导体金红石型TiO2薄膜。建立了一种不使用传统水热法的低温合成方法,在不同温度下获得了不同尺寸和形状的金红石型TiO2纳米颗粒。通过离心将TiO2晶体从反应液中分离出来,在常温条件下干燥。通过沸水沉积TiO2纳米流体,可以形成多孔的半导体TiO2纳米颗粒膜,膜内无裂纹。所得TiO2薄膜将用作染料敏化太阳能电池的TiO2光阳极。
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Synthesis and Deposition of Rutile TiO2 for Dye-Sensitized Solar Cell Applications
The purpose of this research was to produce semiconductor Rutile TiO2 films using a new deposition method on F-doped SnO2 (FTO) glasses i.e. nanofluid boiling method, using TiO2 nanoparticles. A low-temperature synthesis without using conventional hydrothermal methods was established to obtain the Rutile TiO2 nanoparticles with different size and shape under different temperatures. The crystalline TiO2 was separated from the reaction liquid by centrifugation and dried under ambient condition. The current boiling deposition of the TiO2 nanofluid was found to form porous semiconductor TiO2 nanoparticle films without cracks in the deposited TiO2 film. The obtained TiO2 films will be utilized as TiO2 photoanodes in dye-sensitized solar cells.
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