变质石英玉的宝石学特征

Xiaolian Liu, Qing-xin Meng, Xihao Chen, Songliang Deng
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引用次数: 0

摘要

在宝石学上首次报道了变质石英玉。本文利用偏光显微镜、反射显微镜、电子探针、x射线粉末衍射和红外光谱等手段对样品的宝石学特征进行了总结。试验结果表明,样品由再结晶石英和少量低钠长石组成。石英为微晶颗粒,最大粒径为0.01 mm。电子探针放大2 000× s的电子图像(SE)表明,样品具有1 ~ 2 μm微米细尺度相互叠加而成的致密结构。样品的结晶程度从壳层到过渡层再到内部逐渐降低,内部石英大部分为隐晶,看不到晶界。石英电子探针数据中SiO2的质量分数低于理论值。由于蚀变过程中产生H2O,钛铁矿的总化学成分小于100%。红外光谱在900-1 200 cm-1和5 200 cm-1附近有明显的分裂,充分证明该材料为变质形成的含水石英玉石。
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Gemmological Characteristic of Quartzose Jade by Metamorphism
The metamorphic quartzose jade in gemmology is reported for the first time. In this paper, the gemmological characteristics of the samples were summarized by means of polarizing microscope and reflecting microscope, electron probe, X-ray powder diffraction and infrared spectroscopy.The test results showed that the sample is composed of recrystallized quartz and a small amount of low-sodium feldspar. The quartz was a microcrystalline grain with a maximum particle size of 0.01 mm. Electron probe magnification 2 000× second electron image (SE) shows that the sample has a dense structure formed by 1—2 μm micron fine scales superposed with each other. The degree of crystallization of the sample decreases gradually from the shell to the transition layer to the interior and most of the internal quartz was cryptocrystalline and the grain boundaries could not be seen. The mass fraction of SiO2 in the quartz electron probe data is lower than the theoretical value. The total chemical composition of ilmenite is less than 100% due to the production of H2O during alteration.The infrared spectra showed obvious splitting near 900—1 200 cm-1 and 5 200 cm-1, which fully proved that the material was a kind of quartz jade formed by metamorphism that contains water.
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