绿松石伴生矿物辉长石- goyazite的识别特征

Fan Guizhen, Y. Fang, Luo Yue-ping, Chen Jingjing, Men Lijuan, Ren Huicong
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摘要

最近,市场上出现了一种绿松石伴生矿物,其外观与绿松石非常相似。通过常规宝石学检验和薄片观察、电子探针分析、x射线粉末衍射、红外光谱、拉曼光谱、紫外可见分析等方法对该样品进行了研究,结果表明,该样品的主要矿物成分为辉长石、歌雅石,并含有一定量的绿松石等。样品主色为蓝色,部分呈蓝绿色,蓝色不均匀,以圆点或块状为主富集。具有隐晶织构,密度为2.52 g/cm3,折射率约为1.62(点测)。辉长石-戈雅兹石的红外光谱主要吸收峰位于3 585、3 420、3 140、1 320、1 116、1 039 cm-1和604 cm-1,而辉长石-戈雅兹石的拉曼光谱主要吸收峰位于1 104、1 034、987、612、518、257 cm-1和185 cm-1,与绿松石不同。由于这种绿松石伴生矿物难以鉴别,因此应综合运用常规宝石学检测、傅里叶红外光谱仪、拉曼光谱仪、x射线粉末衍射分析和电子探针分析等方法。
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Identification Characteristic of Turquoise Associated Mineral Crandallite-Goyazite
Recently, a kind of turquoise associated mineral has appeared on the market, which is very similar to turquoise in appearance. The authors studied a relevant sample by means of conventional gemmological tests and the other methods including thin-section observation, electron probe analysis, X-ray powder diffraction, infrared spectroscopy, Raman spectroscopy and ultraviolet-visible analysis, etc.The results showed that the main mineral component of the sample is crandallite and goyazite, as well as a certain amount of turquoise, etc. The main colour of the sample is blue, partially bluish green, and the blue colour is uneven, mainly enriched as dots or lumps. It has cryptocrystalline texture with the density of 2.52 g/cm3, and its refractive index is about 1.62 (point measurement). The infrared spectra of crandallite-goyazite show the main absorption peaks at 3 585, 3 420, 3 140, 1 320, 1 116, 1 039 cm-1 and 604 cm-1, and the Raman spectra of crandallite-goyazite show the main peaks at 1 104, 1 034, 987, 612, 518, 257 cm-1 and 185 cm-1, which are different from those of turquoise. Since it is difficult to identify this kind of turquoise associated mineral, conventional gemmological tests, Fourier infrared spectrometer, Raman spectrometer, X-ray powder diffraction analysis and electron probe analysis should be ultilized comprehensively.
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