玄武岩、玻璃和碳织物增强丁二烯弹性体高模量材料的研究

M. M. Kopyrin, A. E. Markov, A. A. Dyakonov, А. G. Tuisov, А. Okhlopkova, A. Kychkin, N. Lazareva
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摘要

提高弹性体的强度和刚度是提高弹性体性能的一个相关课题,它影响橡胶制品的可靠性和耐久性。本文介绍了一种基于SKD-V丁二烯橡胶和玄武岩纤维、玻璃纤维和碳纤维织物增强层的高模量材料制造技术。研究弹性强度特性的结果表明,与未经改性的弹性体相比,增强样品的极限强度显着增加。抗拉强度增加1.7 ~ 2.8倍。与不加筋的橡胶相比,加筋层的橡胶伸长率降低了25 ~ 47倍。高抗拉强度和低伸长率增加抗剪性。经增强织物包覆的弹性体耐磨性试验表明,其耐磨性降低了5.8倍。用电子显微镜研究了增强填料与聚合物之间的磨损和相互作用。微观结构研究表明,纤维与弹性基体之间存在弱接触。在磨损过程中缺乏接触会导致磨料表面纤维的破坏和进一步分离。由于高抗拉强度和低延伸率的结合,增强材料获得高模量性能和横向迁移率。
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Investigation of butadiene-elastomer-based high modulus materials reinforced by basalt, glass, and carbon fabrics
A relevant task in improving the properties of elastomers is to increase their strength and stiffness, which affect the reliability and durability of rubber products. The paper presents a technology for manufacturing high-modulus materials based on SKD-V butadiene rubber and reinforcing layers of fabrics from basalt, glass, and carbon fibers. The results of studying elastic strength properties reveal a significant increase in the ultimate strength of reinforced samples in comparison with an unmodified elastomer. The increase in tensile strength varies from 1.7 to 2.8 times. The addition of reinforcing layers reduced the elongation value by 25 to 47 times compared to rubber without reinforcement. High tensile strength and low elongation increase shear resistance. The wear resistance testing of elastomers coated with reinforcing fabrics shows a decrease in abrasion resistance reduced by a factor of 5.8. Abrasion wear and interaction between the reinforcing filler and the polymer are studied by electron microscopy. The study of the microstructure shows a weak contact between the fiber and the elastomeric matrix. Lack of contact during the abrasion process causes destruction of the fibers on the abrasive surface and their further separation. Due to the combination of high tensile strength and low elongation, the reinforced materials obtain high modulus properties combined with lateral mobility.
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