用具有毛细管性质的材料降低水色度

Yaroslav Radovenchyk, T. Krysenko, M. Poberezhnyi, V. Radovenchyk
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The use of materials with capillary properties is a promising method since it simultaneously ensures the liquid phase transport without excess pressure and water cleaning from various pollutants. This method, used to reduce water chromaticity, found that sufficient efficiency could be provided only for the initial water chromaticity level within 20 - 80° CCS and at pH level within 2.0 - 4.0. Under other conditions, all studied tissue samples as a material for capillary filter, such as cotton, linen, polyester and gabardine, did not provide the value of water chromaticity required for drinking water. Even worse results were obtained for water with initial chromaticity more than 80 degrees. Considering that the described method can provide the maximum efficiency only in a highly acidic medium, it is assumed that the surface charge of the capillary filter fibers and humic acid particles could be the critical factor in the reduction of water chromaticity. 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引用次数: 0

摘要

环境中大量植物和动物有机残留物的存在导致了自然水体的严重污染和水体色度的严重恶化。乌克兰关于饮用水质量的监管文件规定水的色度为20度。因此,在大多数情况下,天然水必须在饮用前进行额外处理。混凝、絮凝、过滤和浮选是目前最常用的水色度正规化方法。所有这些过程都相当复杂和昂贵,需要使用额外的试剂,并导致二次水污染。具有毛细管特性的材料的使用是一种很有前途的方法,因为它同时保证了液相的输送没有过量的压力和水从各种污染物中清洗出来。该方法用于降低水色度,发现只有初始水色度在20 - 80°CCS范围内,pH值在2.0 - 4.0范围内,才能提供足够的效率。在其他条件下,所有作为毛细管过滤材料的组织样本,如棉、麻、涤纶和华达呢,都没有提供饮用水所需的水色度值。对于初始色度超过80度的水,结果更差。考虑到所描述的方法只能在高酸性介质中提供最大的效率,我们假设毛细过滤纤维和腐植酸颗粒的表面电荷可能是降低水色度的关键因素。在较宽的pH范围内,腐殖质颗粒表面主要带负电荷。在pH值2.0 ~ 11.0范围内,纤维素纤维表面也带负电荷。因此,实验结果可以从这个角度来解释。在这些领域根本没有研究数据。采用该方法提高水色度还原效率的可能途径之一是选择具有合适的物理化学表面性能的织物。此外,毛细管过滤过程可以用特殊试剂处理,使纤维表面具有所需的电荷。通过串联多个毛细管过滤器进行水处理是一种很有前途的方法。总的来说,考虑到过滤器设计简单,水处理过程的总成本低,零能量损失,所研究的方法具有很好的工业实施前景,需要更详细的研究。
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Reduction of water chromaticity by materials with capillary properties
The presence of a significant amount of plant and animal organic residues in the environment leads to intensive pollution of natural waters and significant deterioration of water chromaticity. Ukrainian regulatory documents on the quality of drinking water establish a level of 20 degrees for water chromaticity. Hence, in most cases, natural water must be additionally treated before consumption. The coagulation, flocculation, filtration and flotation are today the most widespread methods for normalizing the water chromaticity level. All these processes are quite complex and expensive, require the use  of additional reagents and lead to secondary water pollution. The use of materials with capillary properties is a promising method since it simultaneously ensures the liquid phase transport without excess pressure and water cleaning from various pollutants. This method, used to reduce water chromaticity, found that sufficient efficiency could be provided only for the initial water chromaticity level within 20 - 80° CCS and at pH level within 2.0 - 4.0. Under other conditions, all studied tissue samples as a material for capillary filter, such as cotton, linen, polyester and gabardine, did not provide the value of water chromaticity required for drinking water. Even worse results were obtained for water with initial chromaticity more than 80 degrees. Considering that the described method can provide the maximum efficiency only in a highly acidic medium, it is assumed that the surface charge of the capillary filter fibers and humic acid particles could be the critical factor in the reduction of water chromaticity. In a wide pH range, the surface of the humic particles is charged mainly negatively. The surface of cellulose fibers is also negatively charged in the pH range of 2.0 - 11.0. Therefore, the results of experiments can be explained from this point of view. There are no research data in these fields at all. One of the possible ways to improve the efficiency of water chromaticity reduction by the proposed method is to select fabrics with appropriate physicochemical surface properties. Also, capillary filtration process can be treated with special reagents for giving the fiber surface the required charge. Water treatment by series of several connected capillary filters can be a promising way. In general, given the simplicity of the filter design, low total cost of the water treatment process, and zero energy losses, the studied method is quite promising for industrial implementation and needs more detailed research.
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