纳米氧化锆粉体表面吸附聚丙烯酸铵的红外光谱研究

Fengqiu Tang , Xiaoxian Huang , Lianzhou Wang , Jingkun Guo
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引用次数: 9

摘要

采用漫反射傅立叶变换(DRIFT)光谱法测定了纳米氧化锆粉体表面吸附添加剂的红外光谱。通过制备不同pH值和不同浓度聚丙烯酸酯的氧化锆悬浮液,研究了氧化锆悬浮液的结构信息性质。这些漂移光谱可以提供有关聚丙烯酸酯在氧化锆表面存在的有用信息,包括其电离度和结构。在氧化锆水悬浮液中加入聚丙烯酸酯可以完全改变氧化锆颗粒的表面化学性质和相互作用。
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Infrared spectral studies of ammonium polyacrylate adsorbed on nano-zirconia powder surfaces

The infrared spectra of the additives adsorbed on nano-zirconia powder surfaces were measured by using diffuse reflectance Fourier transform (DRIFT) spectroscopy. The nature of the structural information has been studied by preparing zirconia suspensions at various pH and different concentrations of polyacrylate addition. These DRIFT spectra can provide useful information about polyacrylate existence on zirconia surface including the ionization degree and its configuration. The addition of polyacrylate into zirconia aqueous suspension could completely change the surface chemistry and interaction of zirconia particles.

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