电厂重质燃料油加氢脱硫工艺技术经济分析

A. Khalili-Garakani, M. Jafari
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摘要

在伊朗,发电厂使用液体燃料,如重质燃料油(HFO)或mazut,以防止发电中断。重油中含硫化合物的比例很高,而且缺乏对其进行去除的努力,对环境造成重大损害。本研究的目的是对重油加氢脱硫(HDS)过程进行技术经济分析。结果表明,在体积流量为250 m3/h(含3.5% wt硫化物)的条件下,从HFO中脱除85%的硫化物,总投资和净生产成本分别为3.089亿美元和1.145亿美元/年。此外,灵敏度分析表明,当催化剂负载增加100%时,HFO中含硫化合物的质量百分比将下降15%以上。此外,总资本投资和净生产成本将分别增加6.4%和32%。当气油比提高100%时,HFO中硫化物的质量百分比将下降15.3%以上。此外,总投资和净生产成本将分别增加43.8%和6%。当HDS工艺压力增加100%时,HFO中硫化物的质量百分比将降低20.75%以上。总投资和净生产成本分别增加43%和6.75%。最终,当床层入口温度提高100%时,HFO中硫化物的质量百分比将再降低5%。在有效运行参数中,耗氢量对净生产成本和投资回收期的影响最大,加氢脱硫工艺压力对增加工艺总投资的影响最大。
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Techno-Economic Analysis of Heavy Fuel Oil Hydrodesulfurization Process for Application in Power Plants
In Iran, power plants use liquid fuels such as heavy fuel oil (HFO) or mazut to prevent disruption in power generation. The high percentage of sulfur compounds in HFO and the lack of efforts to remove it, causing significant damage to the environment. The purpose of this research is performing a techno-economic analysis on the Hydrodesulfurization (HDS) process of HFO. The results showed that for removing 85% of sulfur compounds from HFO with a volume flow rate of 250 m3/h that includes 3.5% wt sulfur compounds, the total capital investment and the net production cost are 308.9 million US$ and 114.5 million US$/year, respectively. Besides, the sensitivity analysis indicates that with a 100% increase in the catalyst loading, the mass percentage of sulfur compounds in the HFO will be decreased by 15% more. Also, 6.4% and 32% will add to the total capital investment and net production cost, respectively. With a 100% increase in the gas to oil ratio, the mass percentage of sulfur compounds in the HFO will be decreased by 15.3% more. Also, 43.8% and 6% will be added to the total capital investment and net production cost, respectively. With a 100% increase in the pressure of the HDS process, the mass percentage of sulfur compounds in the HFO will be reduced by 20.75% more. Also, 43% and 6.75% will be added to the total capital investment and net production cost, respectively. Ultimately, with a 100% increase in the inlet temperature of beds, the mass percentage of sulfur compounds in the HFO will be reduced by 5% more. Among the effective operational parameters, hydrogen consumption has the greatest impact on net production cost and payback period, and the pressure of the Hydrodesulfurization process has the greatest impact on increasing the total capital investment of the process.
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