Persistence and transformation of flucetosulfuron herbicide in soil as affected by biotic and abiotic factors

Abstract Effect of biotic and abiotic factors of soil on persistence and transformation of flucetosulfuron was studied in three soils from paddy growing zones of India. Herbicide residues in three soils dissipated with half-life ranging from 1.41 to 8.38 and 0.58 to 1.14 days under sterile and non-sterile conditions, respectively. Acidic pH and soil microbial activity contributed more toward the degradation of flucetosulfuron in soil. Under flooded soils, dissipation was bit slower than under field capacity moisture level. Five transformation products were identified with LC-MS/MS analysis. Ester hydrolysis and sulfonyl urea bridge cleavage seems to be the major transformation pathways for flucetosulfuron in soil.