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MoS2_CNTs_aerogel-based PEDOT nanocomposite electrochemical sensor for simultaneous detection of chloramphenicol and furazolidone in food samples. 基于 MoS2_CNTs_aerogel 的 PEDOT 纳米复合电化学传感器用于同时检测食品样品中的氯霉素和呋喃唑酮。
Pub Date : 2024-09-17 DOI: 10.1080/03601234.2024.2399461
Abhishek K J,Sathish Reddy,Lakshmi B,K N Harish,Yathish N M,Pavanashree R,Madhumitha S
Toxic intermediates in food caused by chloramphenicol (CP) and furazolidone (FZ) have gained interest in research toward their detection. Hence, fast, reliable, and accurate detection of CP and FZ in food products is of utmost importance. Here, a novel molybdenum disulfide-connected carbon nanotube aerogel/poly (3,4-ethylenedioxythiophene) [MoS2/CNTs aerogel/PEDOT] nanocomposite materials are constructed and deposited on the pretreated carbon paste electrode (PCPE) by a facile eletropolymerization method. The characterization of MoS2/CNTs aerogel/PEDOT nanocomposite was analyzed by scanning electron microscopy (SEM), cyclic voltammetry, and differential pulse voltammetry. The modified MoS2/CNTs aerogel/PEDOT nanocomposite has improved sensing characteristics for detecting CP and FZ in PBS solution. For this work, we have studied various parameters like electrocatalytic activity, the effect of scan rates, pH variation studies, and concentration variation studies. Under optimum conditions, the modified electrode exhibited superior sensing ability compared to the bare and pretreated CPE. This improvement in electrocatalytic activity can be the higher conductivity, larger surface area, increased heterogeneous rate constant, and presence of more active sites in the MoS2/CNTs aerogel/PEDOT nanocomposite. The modified electrode demonstrated distinct electrochemical sensing toward the individual and simultaneous analysis of CP and FZ with a high sensitivity of 0.701 µA. µM-1 .cm-2 for CP and 0.787 µA. µM-1 .cm-2 for FZ and a low detection limit of 3.74 nM for CP and 3.83 nM for FZ with good reproducibility, repeatability, and interferences. Additionally, the prepared sensor effectively detects CP and FZ in food samples (honey and milk) with an acceptable recovery range and a relative standard deviation below 4%.
氯霉素(CP)和呋喃唑酮(FZ)在食品中产生的有毒中间体引起了人们对其检测研究的兴趣。因此,快速、可靠、准确地检测食品中的氯霉素和呋喃唑酮至关重要。本文采用简便的电聚合方法,构建了一种新型二硫化钼连接碳纳米管气凝胶/聚(3,4-乙烯二氧噻吩)[MoS2/CNTs 气凝胶/PEDOT]纳米复合材料,并将其沉积在预处理碳浆电极(PCPE)上。通过扫描电子显微镜(SEM)、循环伏安法和差分脉冲伏安法分析了 MoS2/CNTs 气凝胶/PEDOT 纳米复合材料的特性。改性后的 MoS2/CNTs 气凝胶/PEDOT 纳米复合材料在检测 PBS 溶液中的 CP 和 FZ 方面具有更好的传感特性。在这项工作中,我们研究了各种参数,如电催化活性、扫描速率的影响、pH 值变化研究和浓度变化研究。在最佳条件下,与裸露和预处理过的 CPE 相比,改性电极表现出更出色的传感能力。电催化活性的提高可能是由于 MoS2/CNTs 气凝胶/PEDOT 纳米复合材料具有更高的电导率、更大的表面积、更高的异质速率常数以及存在更多的活性位点。改性电极对 CP 和 FZ 的单独和同时分析具有独特的电化学传感功能,灵敏度高达 0.701 µA.µM-1 .cm-2,对 FZ 的灵敏度为 0.787 µA.FZ 的检测限分别为 3.74 nM 和 3.83 nM,具有良好的重现性、可重复性和干扰性。此外,所制备的传感器还能有效检测食品样品(蜂蜜和牛奶)中的 CP 和 FZ,其回收率在可接受的范围内,相对标准偏差低于 4%。
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引用次数: 0
Persistence and degradation of tembotrione in loamy soil: Effect of various organic amendments, moisture regimes and temperatures 腾博硫磷在壤土中的持久性和降解:各种有机添加剂、水分制度和温度的影响
Pub Date : 2024-09-16 DOI: 10.1080/03601234.2024.2403865
Debabrata Ghoshal, Mahima Dixit, Neethu Narayanan, Abhishek Mandal, Priya Saini, Tirthankar Banerjee, Neera Singh, Aman Kumar, Suman Gupta
In the present study, persistence and degradation of tembotrione, a triketone herbicide, was studied in loamy soil collected from maize field. Effects of organic amendments, moistures and temperatu...
本研究对玉米田采集的壤土中三酮除草剂腾博硫磷的持久性和降解情况进行了研究。有机添加剂、湿度和温度对腾博草酮的影响...
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引用次数: 0
Vortex-assisted dispersive micro-solid-phase extraction using silica-supported Fe2O3-modified khat (Catha edulis) biochar nanocomposite followed by GC-MS for the determination of organochlorine pesticides in juice samples 使用二氧化硅支撑的 Fe2O3 改性阿拉伯茶(Catha edulis)生物炭纳米复合材料进行涡流辅助分散微固相萃取,然后采用气相色谱-质谱法测定果汁样品中的有机氯农药含量
Pub Date : 2024-04-30 DOI: 10.1080/03601234.2024.2336572
Kero Assefa Ago, Abera Gure, Shimeles Addisu Kitte, Jemere Kochito, Yerosan Buzayo Balcha
In this paper, dispersive micro-solid phase extraction technique was developed for the purpose of extracting and preconcentrating organochlorine pesticide residues in juice samples before their sep...
本文采用分散微固相萃取技术,对果汁样品中的有机氯农药残留进行萃取和预浓缩,然后再进行分离。
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引用次数: 0
In vitro and in vivo screening of bacterial species from contaminated soil for heavy metal biotransformation activity 体外和体内筛选受污染土壤中重金属生物转化活性的细菌种类
Pub Date : 2024-04-27 DOI: 10.1080/03601234.2024.2343236
Tinatin Doolotkeldieva, Saykal Bobusheva, Mahabat Konurbaeva
Heavy metals (HMs) are widely used in various industries. High concentrations of HMs can be severely toxic to plants, animals and humans. Microorganism-based bioremediation has shown significant po...
重金属(HMs)广泛应用于各行各业。高浓度的重金属会对植物、动物和人类产生严重的毒性。以微生物为基础的生物修复技术已显示出显著的...
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引用次数: 0
Effects of imidacloprid on the survival and biomarker responses of Eristalis tenax larvae (Diptera: Syrphidae): a comparative study between indoor and outdoor exposures 吡虫啉对 Eristalis tenax 幼虫(双翅目:蚜科)存活率和生物标志物反应的影响:室内外暴露的比较研究
Pub Date : 2024-04-25 DOI: 10.1080/03601234.2024.2343598
Michel Mathurin Kamdem, Sipho Sithole, Patricks Voua Otomo
Imidacloprid is a widely used pesticide in agriculture. It is being found in aquatic ecosystems in agricultural regions. This study aimed to evaluate its effects on the survival rates, acetylcholin...
吡虫啉是一种广泛用于农业的杀虫剂。它在农业地区的水生生态系统中被发现。本研究的目的是评估吡虫啉对水生动物的存活率、乙酰胆碱...
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引用次数: 0
Elemental composition and potential health risk of vegetable cultivated in residential area situated close to abandoned gold mine dump: Characteristics of soil quality on the vegetables 在废弃金矿堆场附近居民区种植的蔬菜的元素组成和潜在健康风险:土壤质量对蔬菜的影响
Pub Date : 2024-04-15 DOI: 10.1080/03601234.2024.2339779
Sihle Mngadi, Philiswa Nosizo Nomngongo, Shadung Moja
The presence of toxic metals in residential areas near abandoned gold mine tailings is a major environmental issue. This study mainly aimed to investigate the elemental distribution of both toxic a...
废弃金矿尾矿附近居民区中有毒金属的存在是一个重大的环境问题。本研究的主要目的是调查废弃金矿尾矿附近居民区的有毒金属元素分布。
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引用次数: 0
Enhancement of benzo[a]pyrene mineralization: symbiotic biodegradation by Acinetobacter sp. strain HAP1 in Association with Cyanobacteriota sp. S66 增强苯并[a]芘的矿化:不动杆菌菌株 HAP1 与蓝藻菌株 S66 的共生生物降解作用
Pub Date : 2024-04-11 DOI: 10.1080/03601234.2024.2336554
Mohamed Seddik Oussama Belahmadi, Ala Abdessemed
The ability of Acinetobacter sp. strain HAP1, isolated from petroleum refinery effluent, to eliminate different concentrations (20, 40, 60, 80 and 100 mg/L) of Benzo[a]Pyrene degradation (BaP) was ...
从石油炼制污水中分离出的不动杆菌菌株HAP1对不同浓度(20、40、60、80和100 mg/L)的苯并[a]芘降解(BaP)的消除能力 ...
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引用次数: 0
Molecular docking analysis of chlorpyrifos at the human α7-nAChR and its potential relationship with neurocytoxicity in SH-SY5Y cells 毒死蜱与人类 α7-nAChR 的分子对接分析及其与 SH-SY5Y 细胞神经毒性的潜在关系
Pub Date : 2024-04-10 DOI: 10.1080/03601234.2024.2340929
Lenin J. Ramirez-Cando, Lizeth G. Rodríguez-Cazar, Luis A. Acosta-Tobar, Santiago J. Ballaz
The organophosphate insecticide chlorpyrifos (CPF), an acetylcholinesterase inhibitor, has raised serious concerns about human safety. Apart from inducing synaptic acetylcholine accumulation, CPF c...
有机磷杀虫剂毒死蜱(CPF)是一种乙酰胆碱酯酶抑制剂,已引起人们对其对人体安全性的严重关注。除了诱导突触乙酰胆碱蓄积外,CPF 还会导致...
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引用次数: 0
Polychlorinated biphenyl congeners in water canals and their relationships with water quality parameters: Insights into their risk assessment 水渠中的多氯联苯同系物及其与水质参数的关系:对其风险评估的启示
Pub Date : 2024-04-07 DOI: 10.1080/03601234.2024.2336859
Marwa Tamim A. Abdel-Wareth, Naglaa Zanaty, Rania M. Abd El-Hamid, Hassnaa A. Saleh
Water pollution with pesticides is one of the most important environmental problems. Polychlorinated biphenyls (PCBs) reach water bodies via agricultural discharge. The aim of this study was to det...
杀虫剂造成的水污染是最重要的环境问题之一。多氯联苯 (PCB) 通过农业排放物进入水体。这项研究的目的是确定...
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引用次数: 0
Assessment of chitosan-based adsorbents for glyphosate removal 评估壳聚糖吸附剂去除草甘膦的效果
Pub Date : 2023-12-15 DOI: 10.1080/03601234.2023.2291980
K. G. Zavala-Robles, J. R. Ramos-Ibarra, N. E. Franco Rodriguez, A. Zamudio-Ojeda, A. Cavazos-Garduño, J. C. Serrano-Niño
Exposure to glyphosate produces various toxic effects, due to this, different methods have been evaluated for its elimination. The objective of this work was to formulate chitosan-based adsorbents ...
接触草甘膦会产生各种毒性影响,因此,人们对消除草甘膦的不同方法进行了评估。这项工作的目的是配制壳聚糖基吸附剂 ...
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引用次数: 0
期刊
Journal of Environmental Science and Health, Part B
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