研究了合成二氧化硅和交联聚甲基丙烯酸甲酯作为抗堵剂对电缆物理性能的影响

Baggya Karunarathna, M. Premathilaka, Prashantha Malavi Arachchige, Arunajith Perera
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摘要

与电缆生产过程相关的主要问题之一是绝缘层和护套之间的紧密粘附(阻塞),这是由两个聚合物层之间的静电和范德华相互作用造成的。这使得它们很难在不破坏绝缘的情况下分离。传统的方法是在绝缘层和夹套界面内涂上滑石层,以防止夹套和绝缘层之间的堵塞。然而,保持滑石层的均匀是困难的,滑石颗粒的不均匀分布产生了不光滑的表面。因此,传统的滑石层法在减少堵塞方面效率有限。在这项研究中,使用合成二氧化硅和交联聚甲基丙烯酸甲酯(PMMA)对绝缘和护套进行了表面改性。本研究评估了这两种添加剂对其他物理性能的影响,包括热稳定性、绝缘性、抗拉强度、断裂伸长率和压力稳定性。研究表明,合成二氧化硅的应用成功地减少了绝缘与夹套之间的堵塞,有利于提高绝缘电阻。本研究还估计了用于绝缘和护套复合材料的最佳防堵剂用量。
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Studying the impact of synthetic silica and cross-linked polymethyl methacrylate as anti-blocking agents on the physical properties of electric cables
One of the major problems associated with the production process of cables is the tight adhesion between the insulation and jacket (blocking), which is resulted from electrostatic and Van der Waals interactions between the two polymer layers. It makes them difficult to separate without damaging the insulation. As a conventional approach, a talc layer is applied within the insulation and jacket interface to prevent the blocking between the jacket and insulation. However, maintaining a uniform talc layer is difficult, and the uneven distribution of talc particles produces a non-smooth surface. Therefore, the conventional talc layer method has limited efficiency in reducing the bocking. In this study, a surface modification was done for both the insulation and jacket using synthetic silica and crosslinked polymethyl methacrylate (PMMA). This study evaluated the effect of these two additives on other physical properties, including heat stability, insulation resistance, tensile strength, elongation at break, and pressure stability. This study reveals that the application of synthetic silica has successfully reduced the blocking between insulation and jacket and favorably contributed to increasing insulation resistance. The optimum levels of anti-blocking agents to be used in the insulation and jacket compound have also been estimated by this investigation.
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