不同醋酸乙烯浓度下乙烯-醋酸乙烯共聚物薄膜的热、力学和介电性能研究

A. Kaviarasi, Kumari Mvl, A. Anandhavadivel, P. Ar
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引用次数: 1

摘要

用聚乙烯的共聚物乙烯醋酸乙烯酯(EVA)制备了薄膜。将EVA中醋酸乙烯含量的百分比分别为18%、58%和88%,采用常温溶剂浇铸法制备了该薄膜。氯仿用作醋酸乙烯的溶剂,高速搅拌使分子均匀分散。用不同的表征技术对VA含量分别为18%、58%和88%的EVA薄膜进行了表征。傅里叶变换红外光谱(FTIR)证实了不同VA浓度的EVA膜中存在的官能团,热重分析(TGA)证实了随着VA含量的增加,膜的热稳定性。通过力学研究证实,随着醋酸乙烯含量的增加,拉伸强度、弯曲强度和韧性等力学性能得到改善。研究了EVA中三种醋酸乙烯浓度下的介电性能,结果表明,EVA中醋酸乙烯浓度较高时介电常数为88%,介电常数不变。
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Thermal Mechanical and Dielectric Studies on Thin Films of Ethylene Vinyl Acetate Copolymer with Varying Concentration of Vinyl Acetate
The Ethylene vinyl acetate, a copolymer of polyethylene (EVA) has been used for the preparation of thin films for the investigation. The films are prepared by room temperature using solvent casting method through varying the percentage of vinyl acetate content in EVA as 18%, 58% and 88%. Chloroform is used as a solvent for ethylene vinyl acetate, high-speed stirring resulting the homogenous dispersion of the molecules. The resultant thin films of EVA with 18%, 58% and 88% of VA are characterized under different characterization techniques. The Fourier Transform Infrared Spectroscopy (FTIR) confirms the functional groups present in the EVA films of varying concentrations of VA. Thermo Gravimetric Analysis (TGA) is carried out to confirm the Thermal Stability of the films with increase in VA content. The improvement in mechanical properties like Tensile Strength, Flexural Strength and Toughness with increase in vinyl acetate content is confirmed through mechanical studies. The dielectric properties are studied for all the three concentrations of vinyl acetate in EVA, which shows constant result on the value of dielectric constant at higher the vinyl acetate in EVA as 88%.
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