高性能CH3NH3PbI3-xClx钙钛矿太阳能电池的设计与器件建模研究

N. Shukla, Dhara R. Prajapati, S. Tiwari
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引用次数: 1

摘要

钙钛矿太阳能电池以其廉价、简单、高效的技术在世界范围内得到了广泛的研究。通过建模和仿真,可以对太阳能电池进行优化设计。光学和电学建模是优化钙钛矿太阳能电池厚度、缺陷密度、掺杂密度和材料选择等不同参数的方法,以制备稳定高效的钙钛矿太阳能电池。在本研究中,利用太阳能电池电容模拟器(SCAPS-1D)对太阳能电池进行了电学建模。太阳能电池的结构为n-i-p器件结构。CH3NH3PbI3-xClx作为光吸收活性层,TiO2作为电子输运层,Spiro-OMeTADas空穴输运层,器件结构为FTO/ TiO2/ CH3NH3PbI3-xClx/ Spiro-OMeTAD/Au。开路电压Voc、短路电流密度Isc、填充系数和功率转换效率分别为1.28 V、21.63 mA/cm2、0.78和21.53%。结果表明,该优化参数可用于太阳能电池的实验制作。对阳极的各种金属接触材料进行了研究和分析。
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Investigation on Design and Device Modeling of High Performance CH3NH3PbI3-xClx Perovskite Solar Cells
Perovskite solar cells fabricated with inexpensive and simple technology exhibits high efficiency has witnessed worldwide boom in research. The optimization of solar cell can be done through modeling and simulation. The optical and electrical modeling are the ways to optimize different parameter such as thickness, defect density, doping density and material selection for fabricating stable and highly efficient perovskite solar cells. In this research work, electrical modeling of solar cell is done throughSolar Cell Capacitance Simulator(SCAPS-1D).The architecture of the solar cell is n-i-p device structure. CH3NH3PbI3-xClx acts as light absorber active layer, TiO2 as electron transport layer and Spiro-OMeTADas hole transport layer with device structure FTO/ TiO2/ CH3NH3PbI3-xClx/ Spiro-OMeTAD/Au. The open circuit voltage Voc, short circuit current density Isc, fill factor and power conversion efficiency are 1.28 V, 21.63 mA/cm2, 0.78 and 21.53% respectively. The result showed that the optimize parameter can be applied for fabrication of the solar cell experimentally. Various metal contact materials of the anodeare also studied and analyzed.
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