半乳甘露聚糖作为绿色缓蚀剂对碳钢的防腐性能

S. Abbout, Malak Rehioui, R. Hsissou, M. Zouarhi, D. Chebabe, H. Erramli, N. Hajjaji
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摘要

碳钢在酸性介质中易降解,如酸性剥离。因此,需要保护碳钢免受酸性侵蚀。最常用的保护方法之一是使用缓蚀剂。出于环境原因,研究人员已经研究了新一代的抑制剂,称为绿色抑制剂,对环境的破坏更小,同时提供高防腐蚀的保护效率。本研究旨在评估生物源聚合物作为缓蚀剂在1m HCl溶液中对碳钢腐蚀的影响。从塞拉尼亚(Ceratonia Siliqua L.)种子中分离得到半乳甘露聚糖,并利用傅里叶红外光谱(FTIR)对其结构进行了表征。采用不同的电化学方法(塔菲尔曲线、阻抗图)评价了缓蚀剂浓度和浸泡时间对碳钢耐蚀性的影响。利用紫外可见分析表征了半乳甘露聚糖分子与铁原子形成连接的能力。利用扫描电子显微镜(SEM)和能谱仪(EDS)对腐蚀试样的表面进行了评价。结果表明,半乳甘露聚糖通过物理吸附和化学吸附在金属表面表现为混合型缓蚀剂。此外,该化合物的效率随抑制剂浓度的增加而增加,在浓度为1 g/L时达到86.7%。
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The performance of the Galactomannan as a green inhibitor to protect the carbon steel against corrosion
: Carbon steel suffers from high degradation in an acidic medium like acidic stripping. For this reason, the protection of the carbon steel from the aggressive acidic attacks is required. One of the most common methods of protection is the use of corrosion inhibitors. For environmental reasons, researchers have investigated a new generation of inhibitors, called green inhibitors that cause less damage to the environment while providing high protection efficiency against corrosion. This study aims to evaluate the impact of a bio-sourced polymer as a corrosion inhibitor against carbon steel corrosion in a 1 M HCl solution. Galactomannan was obtained from the Ceratonia Siliqua L. seeds, and its structure was characterized by using Fourier transformation infrared spectroscopy (FTIR). Effects of the inhibitor concentration and immersion time on the corrosion resistance of carbon steel was evaluated using different electrochemical methods (Tafel curves, impedance diagrams). Ability of the Galactomannan molecules to form links with iron atoms was characterized using UV-visible analysis. Surfaces of the corroded specimens was evaluated by using scanning electron microscopy (SEM) and EDS. The results show that the Galactomannan acts as a mixed type inhibitor by physisorption and chemisorption on the metal surface. Besides, the efficiency of this compound increases with the concentration of the inhibitor and reaches a value of 86.7% at a concentration of 1 g/L.
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