论希尔特规律与煤层变质作用的对应关系

M. Antoshchenko, Y. Rudniev, E. Filatieva, M. Filatiev
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摘要

目的。证明所有煤层均符合希尔特规律,若不以挥发分释放量来确定变质程度,而采用直接表征有机质组成变化的指标。方法。规定考虑实验数据,在此基础上,用挥发分产率(V daf)指标确定了10个矿山的煤层与希尔特规则的偏差。通过对比V daf和С r指标中煤层的几何排列及其变质特征,可以分析各煤层的希尔特规律的依从性。发现。借助挥发分释放量指标,无法揭示煤层变质转化的全貌。煤层变质转化的一个指标不能单独全面地同时表征煤的组成和性质的变化。与挥发分释放量相比,有机质中碳的元素含量是确定煤层危险性质的更有意义的指标之一。根据这两个指标,由挥发物产率和碳含量建立的希尔特规律的遵从性是随机的。挥发分释放率不符合希尔特规律的绝对最大值为7.84%,相对最大值为23.08%。碳含量与希尔特规则的最大绝对和相对偏差不超过4%,这在很大程度上是由于取样地点不同。水分,连同挥发性物质的释放和碳含量,是煤层变质转化的一个指标,包括确定其危险性质。单个煤层的矿物杂质含量是随机的。在制订安全进行采矿作业的规章文件时,除了确定煤的组成和性质的变质变化指标外,还必须考虑开采煤层的采矿地质和采矿技术条件。创意。首次建立了用有机质中碳含量代替挥发分释放量指标,消除了煤层变质转化与希尔特规律之间的差异。在这种情况下,与Hilt规则的绝对和相对偏差不超过4%,对应于矿区不同部位碳含量测定的精度。实际意义。研究结果使我们有可能提出建议,改进在预测开采作业期间煤层危险特性表现方面的监管框架。
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On the correspondence of hilt's rule to metamorphic transformations of coal seams
Purpose . Prove the compliance of Hilt's rule for all coal seams, if instead of the release of volatile matter yield to determine the degree of metamorphism, indicators are used that directly characterize changes in the composition of the organic mass. Methodology . Provides for consideration of experimental data, on the basis of which deviations from the Hilt's rule were established for the seams of ten mines using the indicator of volatile matter yield ( V daf ). Comparing the geometric arrangement of coal seams and their metamorphic characteristics, respectively, in indicators of V daf and С о , it is possible to analyze the compliance of each coal seam with the Hilt rule. Findings. With the help of the indicator of the release of volatile matter yield, it is not possible to reveal the picture of metamorphic transformations of coal seams. One indicator of metamorphic transformations of coal seams cannot single-handedly and comprehensively characterize simultaneously changes in both the composition and properties of coals. The elemental content of carbon in the organic mass is one of the more informative indicators in determining the hazardous properties of coal seams compared to the release of volatile matter yield. Compliance with the Hilt rule, established by the volatile matter yield and carbon content, is, according to both indicators, random. The absolute maximum non-compliance with the Hilt rule for the release of volatile matter yield is 7.84%, and the relative one is 23.08%. The maximum absolute and relative deviations from the Hilt rule for carbon content do not exceed 4%, which is largely due to sampling in different parts of the mine fields. Moisture, together with the release of volatile substances and carbon content, is an indicator of metamorphic transformations of coal seams, including determining their dangerous properties. The content of mineral impurities for individual coal seams is random. When developing regulatory documents for the safe conduct of mining operations, in addition to the indicators of metamorphic transformations that characterize the composition and properties of coal, it is necessary to consider the mining-geological and mining-technical conditions for mining coal seams. Originality . For the first time it has been established that the discrepancy between the metamorphic transformations of coal mine seams and the Hilt rule is eliminated if the carbon content in the organic mass is used instead of the indicator of the release of volatile matter yield. In this case, the absolute and relative deviations from the Hilt rule do not exceed 4%, which corresponds to the accuracy of determining the carbon content in different parts of the mine field. Practical implications . The research results make it possible to develop proposals for improving the regulatory framework in terms of predicting the manifestation of hazardous properties of coal seams during mining operations.
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