果胶增强聚酯复合材料的制备及热物性研究

M. Karataş, E. Aydoğmuş
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引用次数: 4

摘要

在本研究中,果胶粉在不饱和聚酯(UP)中均匀混合。为了生产聚酯复合材料,在混合物中加入过氧化甲乙酮(MEKP)和八酸钴(Co Oc)。将获得的复合材料作为凝胶倒入标准模具中,并允许固化24小时。确定了复合材料的一些物理和化学性能,并进行了表征过程。考察了聚酯复合材料的密度、邵氏硬度、导热系数和热稳定性。根据所得结果,将果胶用作聚酯复合材料的填料。傅里叶变换红外光谱(FTIR)显示聚酯聚合物的化学结构没有变化。随着果胶粉增强率0 wt.%、1 wt.%、3 wt.%、5 wt.%和7 wt.%的增加,聚酯复合材料的密度降低。此外,果胶粉作为填料的增强降低了聚酯复合材料的邵氏D硬度。然而,研究发现,随着填料比的增加,聚酯复合材料的导热系数增加。在热分解实验中,随着填料比的增大,复合材料的活化能略有降低。根据优化结果,添加3 wt.%的果胶粉不会对聚酯复合材料的表面形貌和热物理性能产生不利影响。
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Obtaining Pectin Reinforced Polyester Composite and Investigation of Thermophysical Properties
In this study, pectin powder is mixed homogeneously in unsaturated polyester (UP). For the production of polyester composite, methyl ethyl ketone peroxide (MEKP) and cobalt octoate (Co Oc) are added to the mixture. The obtained composite is poured into standard molds as a gel and allowed to cure for 24 hours. Some physical and chemical properties of the composite are determined and characterization processes are carried out. Density, Shore D hardness, thermal conductivity coefficient, and thermal stability of polyester composite are examined. According to the results obtained, pectin is used as a filler in the polyester composite. There is no change in the chemical structure of the polyester polymer with Fourier transform infrared (FTIR) spectroscopy. The density of polyester composites decreases as the reinforcement of 0 wt.%, 1 wt.%, 3 wt.%, 5 wt.%, and 7 wt.% pectin powder increases. Besides, the reinforcement of pectin powder as filler reduces Shore D hardness of the polyester composite. However, it has been observed that the thermal conductivity coefficient of the polyester composite increases as the filler ratio rises. In thermal decomposition experiments of the composite, the activation energy decreases slightly as the filler ratio increases. According to the optimization results, 3 wt.% pectin powder supplementation does not adversely affect both the surface morphology and thermophysical properties of the polyester composite.
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