PE/TiC纳米复合材料的电学性能研究

Yongsen Han, Jian Sun, Guanyu Chen, Zihan Xu, Zhonghua Li
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引用次数: 0

摘要

由于碳化钛(TiC)具有优异的电学和力学性能,制备了聚乙烯(PE)/碳化钛纳米复合材料。填料负荷为0、0.5、1、5和10 wt%。分别采用不同扫描热分析仪、介电谱仪和电导率测试仪对PE/TiC纳米复合材料的结晶度、相对介电常数和直流电导率进行了测量。实验结果表明,PE/TiC纳米复合材料的结晶度随着填料的加入先增大后减小。0.5 wt%和1 wt% PE/TiC纳米复合材料的相对介电常数比纯PE低。5 wt%和10 wt% PE/TiC纳米复合材料的相对介电常数高于纯PE。随着填料用量的增加,PE/TiC纳米复合材料的直流电导率先降低后升高。此外,与纯PE相比,PE/TiC纳米复合材料随温度的升高变化较小。PE/TiC纳米复合材料有利于提高电缆的电性能。
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Study on Electrical Properties of PE/TiC Nano-composites
As titanium carbide (TiC) shows excellent electrical and mechanical properties, polyethylene (PE)/TiC nano-composites are prepared. The filler loading is 0, 0.5, 1, 5 and 10 wt%. The different scanning thermal analyzer, dielectric spectrum instrument and conduction measurement are, respectively, used to measure the crystallinity, relative permittivity and dc conductivity of PE/TiC nano-composites. Experimental results show that the crystallinity of PE/TiC nano-composites firstly increases and then deceases with filler loading. The 0.5 wt% and 1 wt% PE/TiC nano-composites show lower relative permittivity than pure PE. The 5 wt% and 10 wt% PE/TiC nano-composites show higher relative permittivity than pure PE. The dc conductivity of PE/TiC nano-composites firsly decrease then increase with the increasing filler loading. In addition, compared with pure PE, PE/TiC nano-composites have smaller change with the increasing temperature. The PE/TiC nano-composites are beneficial to improve the electrical performance of cables.
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