废锰锌化学电流源活性物质的电化学处理

G. G. Pechenova, A. Chernik
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引用次数: 0

摘要

为了加工初级锰锌化学电流源,优化了活性物质组分的处理和分离工艺。该技术包括以粉末和涂层的形式提取锌。锰化合物将以二氧化锰的形式提取,同时将废物的危害等级降至第四。用滴定法测定浸出后电解液的定量和定性组成。浸出液中锌Zn2+和锰Mn2+离子浓度最高,分别为34和41.36 g/dm3。溶液中存在少量Fe2+铁离子。采用电解法对废锰锌电流源的活性物质进行酸、碱溶液的浸出,以镀层形式提取锌。
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Electrochemical processing of the active mass of spent manganese-zinc chemical current sources
In order to process primary manganese-zinc chemical current sources, the technology for processing and separation of active mass components is optimized. The technology involves the extraction of zinc in the form of powder and in the form of coatings. Manganese compounds will be extracted in the form of manganese dioxide, while reducing the hazard class of waste to the fourth. The quantitative and qualitative composition of the electrolyte after leaching was determined by titrometric method. The highest concentration in the leaching electrolyte was observed for zinc Zn2+ and manganese Mn2+ ions, their concentrations were 34 and 41.36 g/dm3, respectively. Fe2+ iron ions were present in small amounts in the solutions. Using electrolytic processing of acid and alkaline solutions by leaching the active mass of spent manganese-zinc current sources, zinc in the form of coating was extracted.
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发文量
38
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