Polymersynthesen repetitive的‐alkylierungen

R. C. Schulz, G. Hochberg, F. Walter
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引用次数: 2

摘要

最初由Marvel使用的重复n -烷基化反应被证明是一种非常通用的合成多阳离子的方法。Rembaum为这类聚合物引入了“碘烯”这个名字。在讲座的第一部分,我们将介绍一些单链离子的例子。第二部分展示了重复n -烷基化如何用于合成螺旋聚合物。在这些双链聚合物中,主链上的两个螺旋共轭环共有一个中心季氮(螺旋偶氮聚合物或螺旋偶氮聚合物)。
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Polymersynthesen durch repetitive N‐alkylierungen
The repetitive N-alkylation reaction, at first used by Marvel, turned out to be a very versatile method for the synthesis of polycations. Rembaum introduced the name ionenes for this type of polymers. In the first part of the lecture some examples of single-stranded ionenes are described. The second part shows how the repetitive N-alkylation can be used for the synthesis of spiro polymers. In these double-stranded polymers two spiro-conjugated rings of the main chain have a central quaternary nitrogen in common (spiro-ionenes or spiro-azonia polymers)
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