取代乙烯氧基环丙烷与硫醇的加合物作为PVC的热稳定剂

R. Shahnazarli
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引用次数: 0

摘要

在聚氯乙烯的基础上,研制了以邻苯二甲酸二辛酯为增塑剂、硬脂酸钙锌为复合热稳定剂、硫苯酚和乙二硫醇加合物为共稳定剂和杀菌剂的组合物。研究了所合成的组合物的热性能,并研究了所合成的含硫加合物对组合物热稳定性和颜色变化的影响。通过实验揭示了PVC组合物结构中加合物的抗真菌活性。结果表明,加合物加入到组合物结构后,其化学结构并没有发生本质的变化。加合物作为共稳定剂的组合物在热稳定性、颜色稳定性和抗真菌活性等指标上均有改善。
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ADDUCTS OF SUBSTITUTED VINYLOXYCYCLOPRFOPANES WITH THIOLS AS THERMOSTABILIZERS OF PVC
The compositions on the basis of PVC, containing dioctyl phthalate as a plasticizer, complex thermal stabilizers – calcium and zinc stearates and adducts of thiophenol and ethanedithiol with gemdiglycidyloxymethylsubstituted cyclopropylvinyl ether as co-stabilizers and biocidal additives were developed. Thermal properties of the developed compositions were investigated and the influence of the synthesized sulfur-containing adducts on the thermal stability and color change of the compositions studied. The tests were carried out to reveal the antifungal activity of adducts in the structure of PVC compositions. It found that the chemical structure of adducts after introduction into the structure of compositions was not essentially changed. The compositions with the participation of adducts as co-stabilizers acquired improved indices on thermal stability, color stability and antifungal activity.
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