粉末冶金法制备C60富勒烯改性的纳米结构应变硬化铝镁合金。第二部分。镁浓度对物理力学性能的影响

I. Evdokimov, R. R. Khayrullin, R. Bagramov, S. Perfilov, A. Pozdnyakov, V. Aksenenkov, B. Kulnitskiy
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摘要

本文将继续研究镁对C60富勒烯改性纳米结构应变硬化铝镁合金的组织相组成和物理力学性能的影响[1]。先前获得的机械合金复合粉末[1]采用直接热挤压法固结。基于对机械合金化和热处理过程中组织和相组成形成的研究,选择了固结参数。结果表明,随着镁浓度的增加,挤压纳米复合材料的力学性能得到改善,C60富勒烯改性添加剂在300℃时稳定了镁在铝中的α固溶体的晶粒结构,减缓了镁在铝中的分解。在类似的热压处理下,未加C60修饰的Al82Mg18 (AMg18)的α固溶体晶格常数降低,平均晶粒尺寸增大。这些过程伴随着γ、β′和β相的顺序形成,而γ和β′是中间相。挤压试样的晶粒结构是用这种方法获得的典型材料——晶粒紧密排列、拉长并沿挤压轴取向。挤压试样的晶粒结构继承了机械合金化粉末的形貌。因此,机械合金化方法之后的强塑性变形(挤压)提高机械性能显著。抗拉强度达到880 MPa的材料;极限抗弯强度为1100 MPa;显微硬度可达3300 MPa;同样的密度为2.4 ~ 2.6 g/cm3。这一结果表明,采用粉末冶金技术制备具有良好物理力学性能的C60富勒烯改性纳米复合材料具有广阔的前景。
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Nanostructured strain-hardened aluminum-magnesium alloys modified by C60 fullerene obtained by powder metallurgy Part 2. The effect of magnesium concentration on physical and mechanical properties
This paper is intended to continue the studies of magnesium effects on the structural phase composition, physical and mechanical properties of the nanostructured strain-hardened aluminum-magnesium alloys modified with C60 fullerene [1]. Previously obtained mechanically alloyed composite powders [1] were consolidated by direct hot extrusion method. Consolidation parameters were chosen based on previous studies of the structure and phase composition formation during mechanical alloying and heat treatment. It was found that an increase in magnesium concentration improves mechanical properties of extruded nanosructured composite materials, and additives modified by C60 fullerene stabilize the grain structure and slow down decomposition of α solid solution of magnesium in aluminum to 300 °C. Under similar thermobaric treatment Al82Mg18 (AMg18) not modified with C60 demonstrates a reduced α solid solution lattice constant and an increased average crystallite size. These processes are accompanied by sequential formation of γ, β′, and β phases, while γ and β′ are intermediate phases. The grain structure of extruded samples is typical for materials obtained in this way – grains are closely packed, elongated and oriented along the extrusion axis. The grain structure of extruded samples inherits the morphology of mechanically alloyed powders. Thus, mechanical alloying methods followed by intense plastic deformation (extrusion) improved mechanical properties significantly. Materials with ultimate tensile strength of 880 MPa; ultimate bending strength of 1100 MPa; microhardness up to 3300 MPa; and with the same density of 2.4–2.6 g/cm3 were obtained. This result demonstrates the prospects for using powder metallurgy techniques in the production of new nanostructured composite materials modified by C60 fullerene with improved physical and mechanical properties.
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