利用可伸缩滚涂工艺制备仿生微/纳米纹理粗糙表面

S. Chockalingam, J. Ryu, Md. Didarul Islam, Myers Harbinson
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摘要

仿生微/纳米表面纹理粗糙形貌在超疏水性、自清洁表面、防冰涂层、防生物污垢和减阻表面等方面有许多应用。自然界中层次复杂的表面形貌的作用是放大疏水性,最大限度地提高抗污能力。因此,一个类似的微纳米级的三维地形表面的灵感来自大自然,使用一个简单的和可扩展的两辊涂层工艺。这一过程是基于与两个滚筒之间的非牛顿流体剪切有关的罗纹不稳定性。聚合物复合材料在去除剪切应力后,由于高粘度的恢复而保持了变形的形状。通过剪切速率、毛细数和表面粗糙度参数(如Wenzel因子和峰密度)研究了工艺条件与织构结构的关系。结果表明:试样的Wenzel粗糙度系数随剪切速率的增加而增大,达到一定值后减小;同样,样品中的峰密度随着毛细管数的增加而增加,直到特定值,然后减小。这些具有分层纹理图案的仿生表面采用双辊涂层工艺生产,在超疏水、抗生物污垢和减阻应用中显示出巨大的潜力。
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Fabrication of Bioinspired Micro/Nano Textured Rough Surfaces Through the Scalable Roll Coating Process
Bioinspired Micro/Nano textured rough topography of a surface has many applications in super-hydrophobicity, self-cleaning surface, anti-icing coatings, anti-biofouling, and drag reduction surfaces. The role of hierarchical and complex surface topography in nature is to amplify the hydrophobicity and maximize the fouling resistance. Thus, a similar micro- and nano-scale 3-D topographic surfaces inspired from the nature were fabricated using a simple and scalable two roll coating process. This process was based on the ribbing instabilities associated with the shearing of non-Newtonian fluids between two rollers. The polymer composite retains the deformed shape due to the recovery of high-viscosity after removing the shear stress. The relationship between the process conditions and the textured structure were studied with the shear rate, capillary number and the surface roughness parameters (e.g., Wenzel factor and density of peaks). The results showed that the samples’ Wenzel roughness factor increased with the increase in shear rate up to a particular value and then decreased. Similarly, the density of peaks in the sample increased with an increase in capillary number up to a particular value and then decreased. These bioinspired surfaces with hierarchical textured patterns produced using two roll coating process show a tremendous potentiality to be used in super-hydrophobic, anti-biofouling, and drag reduction applications.
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