钢结构防腐涂料的可持续改进方法

P. Soroushian, A. Balachandra, R. Weerasiri, N. Darsanasiri, Nastran Abdol
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摘要

腐蚀是影响钢结构安全和使用寿命的主要因素。防腐涂料通常用于保护暴露在不同侵蚀环境中的钢结构。本研究评估了生物基离子交换剂作为一种可持续改善防腐涂层的方法。考虑了两种基材聚合物涂料(乙烯基和煤焦油环氧树脂)。以下类型和剂量的生物基离子交换剂在这些涂层中进行了评估:(i)强碱离子交换纤维素,OH, PO4, SiO3, BO3, NO2, SO4和NO3形式在树脂重量的1%;(ii) 1 wt.% H型柠檬酸淀粉交换剂;(iii) 2 wt.% OH形式的强碱离子交换纤维素。此外,在1和2 wt.%的浓度下,考虑OH形式的强碱离子交换树脂作为对照。根据盐雾腐蚀、防潮性、拉脱强度和耐磨性测试的结果,对不同的涂层配方进行了评估。研究发现,在保护涂层中引入某些生物基离子交换剂是一种有效的方法,可以提高涂层的耐腐蚀性、粘附能力、防潮稳定性和耐磨性。
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A SUSTAINABLE APPROACH TO IMPROVEMENT OF CORROSION PROTECTION COATINGS FOR STEEL STRUCTURES
            Corrosion is a primary factor compromising the safety and service life of steel structures. Corrosion protection coatings are generally employed for protection of the steel structures that are exposed to different aggressive environments. This research evaluated the use of biobased ion exchangers as a sustainable means of improving corrosion protection coatings. Two base polymer coatings (vinyl and coal-tar epoxy) were considered.  The following types and dosages of biobased ion exchangers were evaluated in these coatings: (i) strong-base ion exchange cellulose in OH, PO4, SiO3, BO3, NO2, SO4 and NO3 forms at 1% by weight of resin; (ii) weak-acid starch citrate ion exchanger in H form at 1 wt.%; and (iii) strong-base ion exchange cellulose in OH form at 2 wt.%. In addition, a strong-base ion exchange resin in OH form was considered at 1 and 2 wt.% as control.  Different coating formulations were evaluated based on the outcomes of salt-fog corrosion, moisture resistance, pull-off strength, and abrasion resistance tests. The introduction of certain biobased ion exchangers in protective coatings was found to be an effective means of achieving improved levels of corrosion resistance, adhesion capacity, moisture stability and abrasion resistance.
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