合金元素对Ti-Al-Mo-Zr钛合金强化相及凝固组织的影响

J. Tang, Cui Liang, Chenkun Xu, J. Li
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摘要

本文主要研究了Ti-Al-Mo-Zr-Si医用钛合金中强化相的组成、特征析出温度和强化相的组成范围,以及元素变化对强化相含量和显微组织的影响。推动了钛合金粉末冶金热力学工艺的制定,以及合金热加工和固溶时效工艺的制定。本文采用Panda热力学软件计算钛合金材料的多组分合金热力学和多组分相图。获得了Al、Mo、Zr、Si等元素对强化相析出及凝固组织相变含量的影响。发现Mo的含量大于2 wt.% β相变析出角。同时,为了避免Mo5Si3和M3Si等析出物的过量,Mo的含量应小于4.6 wt.%。Zr的含量可保持在1.5 wt.%左右。如果考虑材料的时效析出,可以控制在2wt .%以下。本文的研究内容是钛粉末冶金技术和快速成型技术的基础和改进。
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Effect of Alloying Elements on Strengthening Phase and Solidification Structure of Ti-Al-Mo-Zr Titanium Alloy
This paper mainly studies the composition of strengthening phase, characteristic precipitation temperature and composition range of strengthening phase in Ti-Al-Mo-Zr-Si medical titanium alloy, and the influence of element changes on the content and microstructure of strengthening phase. Promote the formulation of thermodynamic process of titanium alloy powder metallurgy, as well as the formulation of alloy hot working and solid solution aging process. In this paper, Panda thermodynamic software is used to calculate the multicomponent alloy thermodynamics and multicomponent phase diagram of titanium alloy materials. The effects of Al, Mo, Zr, Si and other elements on the precipitation of strengthening phase and the phase transformation content of solidification structure were obtained. It is found that the content of Mo is more than 2 wt.% β phase transition precipitation angle. Meanwhile, in order to avoid the excess of precipitates such as Mo5Si3 and M3Si, the content of Mo should be less than 4.6 wt.%. The content of Zr can be maintained at about 1.5 wt.%. If the aging precipitation of the material is considered, it can be controlled to be less than 2 wt.%. The content of this paper is the basis and improvement of titanium powder metallurgy technology and rapid prototyping technology.
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