新鲜蔬菜及其加工产品中硝酸盐的测定

E. O. Markova, Michael Yu. Dyakov
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摘要

在一般氮循环中,人为来源的硝基化合物的数量在稳步增加,这导致产物中硝酸盐的增加,从而增加了人体的硝酸盐-亚硝酸盐负荷。这项研究的目的是确定生蔬菜及其加工产品中硝酸盐的含量。选择硝酸盐含量高(甜菜根、香菜、萝卜、葱)、中等(西葫芦、胡萝卜、黄瓜)和低(土豆、番茄、洋葱)的蔬菜作为研究对象。为了定性测定硝酸盐的含量,采用了与二苯胺的反应。为了进行定量测定,使用离子选择电极ECOM-NO3对ph计量物Ecotest 2000进行了离子测定。在研究过程中发现,进入Magnit零售连锁店的蔬菜,除了萝卜和西葫芦外,硝酸盐含量没有超过MPC。当用微波炉烹饪时,硝酸盐的含量会急剧增加。当蔬菜“煮熟”时,蔬菜中的硝酸盐含量会减少,但肉汤中的硝酸盐含量会增加。随着长时间的热处理,蔬菜和肉汤中硝酸盐的含量都会增加。在封闭容器中冷冻和解冻蔬菜时,硝酸盐含量会下降,而在开放容器中解冻时,硝酸盐含量会急剧上升。因此,建议不要在烹饪过程中使用微波炉。煮的时候先把水倒掉,再倒入新的水煮熟。现成的蔬菜不应该留在肉汤中,因为离子会反向吸附。蔬菜应该在封闭的容器中解冻。
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Determination of nitrates in fresh vegetables and their processed products
The number of nitro compounds of the anthropogenic origin in the general nitrogen cycle is steadily increasing, which leads to an increase in nitrates in products and increases the nitrate-nitrite load on the human body. The aim of the study was to determine the amount of nitrates in raw vegetables and their processed products. Vegetables with high (beetroot, cilantro, radish, green onion), medium (zucchini, carrot, cucumber) and low nitrate content (potato, tomato, onion) have been selected as the objects of the study. For the qualitative determination of nitrates the reactions with diphenylamine have been carried out. For quantitative determination, the ionometric determination of the pH-meterionomer Ecotest 2000 has been carried out using an ion-selective electrode ECOM-NO3. In the course of the study, it has been found out that the vegetables entering the Magnit retail chain do not exceed the MPC in terms of nitrate content, with the exception of the radish and zucchini. When cooking in a microwave oven the amount of nitrates increases dramatically. When cooking vegetables «until ready», the amount of nitrates in vegetables decreases, but their amount in broths increases. With prolonged heat treatment the amount of nitrates increases both in vegetables and in the broth. When freezing and defrosting vegetables in a closed container, a decrease in nitrates is observed, and when defrosting in an open container, the level of nitrates increases sharply. Thus it is recommended not to use a microwave oven during the cooking process. During boiling first drain the water, then pour in new one and boil until ready. Ready-made vegetables should not be left in the broth due to the reverse adsorption of ions. Vegetables should be defrosted in a closed container.
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