{"title":"乙二硫醇与烷基和环烷基取代的亚甲基二氧索烷双加合物在聚氯乙烯合成中的应用","authors":"F.Kh. Yusifli, N. Aliyeva, G. Ramazanov","doi":"10.32737/2221-8688-2023-1-72-77","DOIUrl":null,"url":null,"abstract":"By free radical addition of ethanedithiol to alkyl- and cycloalkyl-substituted methylene dioxolanes, the bis-adducts tested then as a plasticizer for PVC have been obtained. It has been established as a result of the carried out investigations that the introduction of the synthesized compounds into PVC composition improves the physical-mechanical properties, which has been connected with the availability of sulfur atoms, carbonyl groups and ether bond in the molecules of bis-adducts. The high operational indices from PVCplastics indicate good plasticizing properties of the synthesized bis-adducts, and therefore they can be recommended for practical use.","PeriodicalId":10015,"journal":{"name":"Chemical Problems","volume":"217 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"USE OF BIS-ADDUCTS OF ETHANEDITHIOL WITH ALKYL- AND CYCLOALKYL SUBSTITUTED METHYLENE DIOXOLANES IN THE COMPOSITION OF POLYVINYL CHLORIDE\",\"authors\":\"F.Kh. Yusifli, N. Aliyeva, G. Ramazanov\",\"doi\":\"10.32737/2221-8688-2023-1-72-77\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"By free radical addition of ethanedithiol to alkyl- and cycloalkyl-substituted methylene dioxolanes, the bis-adducts tested then as a plasticizer for PVC have been obtained. It has been established as a result of the carried out investigations that the introduction of the synthesized compounds into PVC composition improves the physical-mechanical properties, which has been connected with the availability of sulfur atoms, carbonyl groups and ether bond in the molecules of bis-adducts. The high operational indices from PVCplastics indicate good plasticizing properties of the synthesized bis-adducts, and therefore they can be recommended for practical use.\",\"PeriodicalId\":10015,\"journal\":{\"name\":\"Chemical Problems\",\"volume\":\"217 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Problems\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.32737/2221-8688-2023-1-72-77\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Problems","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32737/2221-8688-2023-1-72-77","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
USE OF BIS-ADDUCTS OF ETHANEDITHIOL WITH ALKYL- AND CYCLOALKYL SUBSTITUTED METHYLENE DIOXOLANES IN THE COMPOSITION OF POLYVINYL CHLORIDE
By free radical addition of ethanedithiol to alkyl- and cycloalkyl-substituted methylene dioxolanes, the bis-adducts tested then as a plasticizer for PVC have been obtained. It has been established as a result of the carried out investigations that the introduction of the synthesized compounds into PVC composition improves the physical-mechanical properties, which has been connected with the availability of sulfur atoms, carbonyl groups and ether bond in the molecules of bis-adducts. The high operational indices from PVCplastics indicate good plasticizing properties of the synthesized bis-adducts, and therefore they can be recommended for practical use.