恒磁场效应对难焊聚乙烯-聚丙烯接头纳米结构组织和性能的影响

V. Demchenko, M. Iurzhenko
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引用次数: 0

摘要

利用WAXS和SAXS方法发现,恒定的磁场作用于聚合物熔体(即在聚合物处于粘流状态时,结构元件具有最大的迁移率),会形成轴与磁场作用方向重合的定向焊接接头结构。由于聚合物熔体中磁性各向异性大分子和聚集体的取向,这种效应导致了焊缝操作性能的改善。根据力学试验结果,确定了PE-80/PP-80接头在恒定磁场作用下(横向作用于焊接轴)焊接的抗拉强度为12 MPa,无磁场作用焊接的抗拉强度为6 MPa。
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Peculiarities of constant magnetic field effect on the nanostructural organization and properties of hard-to-weld polyethylene-polypropylene joints
Using WAXS and SAXS methods it was founded that constant magnetic field effect on the melt of polymers (i.e. on the polymers in viscous-flow status, where the structure elements have the maximum mobility) causes formation of oriented welded joint structure with the axle coincides with the magnetic field effect direction. This effect causes improvement of operation properties of the welds due to the orientation of magnet-anisotropic macromolecules and aggregates in the polymer melts. Basing on the mechanical tests results it was founded that tensile strength of PE-80/PP-80 joint welded under the effect of constant magnetic field (acting transversally to the welding axle) is 12 MPa, and of welded without magnetic field effect is 6 MPa.
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