作为下一代太阳能电池组件的CdO/ZnO多量子阱

V. Venkatachalapathy, A. Galeckas, A. Kuznetsov
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引用次数: 2

摘要

本文报道了用金属气相外延法在c面和r面蓝宝石衬底上生长的ZnxCd1-xO/ZnO MQW应变结构的时间分辨和稳态光致发光(PL)研究。通过x射线衍射测量证实了所有MQW结构的高结晶质量。在PL光谱中没有与ZnO势垒相关的发射,这意味着量子阱中存在有效的载流子约束。光跃迁估计的内置电场约为1.75 MV/cm。从量子约束和应变引起的内部电场调制的角度讨论了观测到的光谱和载流子寿命的变化。
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CdO/ZnO multiple quantum wells as components for next generation solar cells
We report on time-resolved and steady state photoluminescence (PL) studies of strained ZnxCd1-xO/ZnO MQW structures grown on c-plane and r-plane sapphire substrates by Metaloranic Vapor Phase Epitaxy. The high crystalline quality of all MQW structures was confirmed by X-ray diffraction measurements. No emission related to ZnO barriers could be resolved in PL spectra implying effective carrier confinement in the quantum wells. The estimated built-in electric field from optical transition is of the order of ~ 1.75 MV/cm. The observed spectral and carrier lifetime variations are discussed in terms of quantum confinement and internal electric field modulation induced by strain.
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