现代化学侦察与控制技术手段在爆炸物探测与识别中的应用

В.А. Иноземцев, И.Н. Ефимов, А.А. Позвонков, А.С. Самородов, В.Н. Пономарев, С.С. Колбинев
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引用次数: 0

摘要

对现代化学侦察技术手段和化学管制专用设备能力的分析表明,通过识别地雷和爆炸装置中包含的炸药和相关的工艺杂质,可以快速探测地雷和爆炸装置。这项工作的目的是分析利用现代化学侦察和控制技术手段探测和识别爆炸物的可能性。为了实现这一目标,作者对化学侦察技术手段的分析特点和特点及其所实施的指示方法进行了评价,以确定检测和识别电子能谱成分的可能性。本文介绍了利用离子迁移率谱法(IMS)的特殊军用气体探测器来确定炸药气相存在的可能性。对过氧化物和含氮炸药的理化性质进行了分析,并将含氮炸药(TNT、RDX、渗透石、硝化甘油、二硝基甲苯)的气相可达浓度与IMS方法的计算灵敏度(~10 ~10 mg/L)进行了比较。利用红外傅立叶光谱和拉曼散射的便携式化学控制技术手段,可以对液体和固体聚集态的痕量炸药进行鉴别。提出了通过建立爆炸物及其伴生工艺杂质光谱数据专用数据库来扩展这些技术手段功能的方法。在IMS气体探测器的控制软件中加入额外的频谱库,必须与操作员实现操作模式的程序选择和数据库切换的可能性相结合。
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Application of Modern Technical Means of Chemical Reconnaissance and Control for the Detection and Identification of Explosives
The analysis of the capabilities of modern technical means of chemical reconnaissance and special equipment of chemical control indicates the possibility of quick detection of mined and explosive devices (EDs) by identification of the explosives included in the EDs and related technological impurities. The purpose of this work is to analyze the possibilities of using modern technical means of chemical reconnaissance and control for the detection and identification of explosives. In order to achieve this goal, the authors assessed the analytical characteristics and features of the technical means of chemical reconnaissance and the indication methods implemented in them to determine the possibility of detecting and identifying the components of the EDs. The article shows the possibility of using special military gas detectors operating on the basis of the ion mobility spectrometry (IMS) method to confirm the presence of the vapor phase of explosives. The assessment was carried out on the basis of an analysis of the physicochemical properties of peroxides and nitrogen-containing explosives and a comparison of the achievable concentrations of the vapor phase of nitrogen-containing explosives (TNT, RDX, pentrite, nitroglycerin, dinitrotoluene) with the results of the calculated sensitivity of the IMS method (~10–10 mg/L). It has been established that trace amounts of explosives in liquid and solid states of aggregation can be identified by portable technical means of chemical control, operating on the basis of infrared Fourier spectroscopy and Raman scattering. The ways of expanding the functionality of these technical means by creating specialized databases of spectral data of explosives and accompanying technological impurities are proposed. The inclusion of an additional spectrum bank in the control software of IMS gas detectors must be combined with the implementation of the possibility of program selection of operating modes and database switching by the operator.
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