多环桥接烃羟基氨基衍生物的制备及其抗菌性能研究

M.B. Alaskarova
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引用次数: 0

摘要

本文介绍了环戊二烯和环己-1,3-二烯部分氢化缩合产物C10-C12三环邻氨基醇的两阶段制备研究结果,在含钴多氧钼酸盐存在下,用过氧化氢将它们环氧化,然后用二乙胺、啉或哌啶对氧化物进行氨解。合成的化合物的结构经IK、1H NMR和波谱确证。对n -取代氨基醇的抗菌性能研究表明,n -取代氨基醇作为M-8发动机油的抗菌添加剂是有效的。
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PREPARATION OF HYDROXYAMINO DERIVATIVES OF POLYCYCLIC BRIDGING HYDROCARBONS AND THEIR ANTIMICROBIAL PROPERTIES
The paper present results of studies of the two-stage preparation of C10-C12 tricyclic vicinal amino alcohols from partially hydrogenated condensation products of cyclopentadiene and cyclohexa-1,3-diene, by epoxidizing them with hydrogen peroxide in the presence of cobalt-containing polyoxomolybdate, followed by aminolysis of the oxidate with diethylamine, morpholine, or piperidine. The structure of the synthesized compounds was confirmed by IK and 1H NMR and spectroscopy. The research into the antimicrobial properties of N-substituted amino alcohols showed their effectiveness as antimicrobial additives to M-8 engine oil.
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