{"title":"多环桥接烃羟基氨基衍生物的制备及其抗菌性能研究","authors":"M.B. Alaskarova","doi":"10.32737/2221-8688-2022-3-271-276","DOIUrl":null,"url":null,"abstract":"The paper present results of studies of the two-stage preparation of C10-C12 tricyclic vicinal amino alcohols from partially hydrogenated condensation products of cyclopentadiene and cyclohexa-1,3-diene, by epoxidizing them with hydrogen peroxide in the presence of cobalt-containing polyoxomolybdate, followed by aminolysis of the oxidate with diethylamine, morpholine, or piperidine. The structure of the synthesized compounds was confirmed by IK and 1H NMR and spectroscopy. The research into the antimicrobial properties of N-substituted amino alcohols showed their effectiveness as antimicrobial additives to M-8 engine oil.","PeriodicalId":10015,"journal":{"name":"Chemical Problems","volume":"34 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"PREPARATION OF HYDROXYAMINO DERIVATIVES OF POLYCYCLIC BRIDGING HYDROCARBONS AND THEIR ANTIMICROBIAL PROPERTIES\",\"authors\":\"M.B. Alaskarova\",\"doi\":\"10.32737/2221-8688-2022-3-271-276\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The paper present results of studies of the two-stage preparation of C10-C12 tricyclic vicinal amino alcohols from partially hydrogenated condensation products of cyclopentadiene and cyclohexa-1,3-diene, by epoxidizing them with hydrogen peroxide in the presence of cobalt-containing polyoxomolybdate, followed by aminolysis of the oxidate with diethylamine, morpholine, or piperidine. The structure of the synthesized compounds was confirmed by IK and 1H NMR and spectroscopy. The research into the antimicrobial properties of N-substituted amino alcohols showed their effectiveness as antimicrobial additives to M-8 engine oil.\",\"PeriodicalId\":10015,\"journal\":{\"name\":\"Chemical Problems\",\"volume\":\"34 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Problems\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.32737/2221-8688-2022-3-271-276\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Problems","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32737/2221-8688-2022-3-271-276","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
PREPARATION OF HYDROXYAMINO DERIVATIVES OF POLYCYCLIC BRIDGING HYDROCARBONS AND THEIR ANTIMICROBIAL PROPERTIES
The paper present results of studies of the two-stage preparation of C10-C12 tricyclic vicinal amino alcohols from partially hydrogenated condensation products of cyclopentadiene and cyclohexa-1,3-diene, by epoxidizing them with hydrogen peroxide in the presence of cobalt-containing polyoxomolybdate, followed by aminolysis of the oxidate with diethylamine, morpholine, or piperidine. The structure of the synthesized compounds was confirmed by IK and 1H NMR and spectroscopy. The research into the antimicrobial properties of N-substituted amino alcohols showed their effectiveness as antimicrobial additives to M-8 engine oil.