多壁碳纳米管聚苯乙烯与增韧聚碳酸酯纳米复合材料的比较研究

Nisha Bagotia
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引用次数: 0

摘要

电子系统和电信的广泛发展导致了一种新型的污染,即电磁干扰(EMI)。电磁干扰已成为一个重大问题,不仅影响电子设备的正常工作,而且对人类的健康产生有害影响[1,2]。一般来说,手机、雷达、无线电收发器、微波炉等各种电子设备是产生电磁干扰的主要原因[3,4]。电磁波的长时间暴露也被认为是强致癌物[5]。因此,需要适当的屏蔽来降低电磁波的影响。通常使用导电或磁性填料作为EMI屏蔽材料,因为这些材料具有与入射电磁波的耦合电场和磁场相互作用的能力[6,7]。金属及金属负载复合材料作为电磁干扰屏蔽材料已得到广泛应用,但其密度大、易腐蚀、加工不便等缺点限制了其实际应用。与金属相比,碳纳米材料已成为生产电磁干扰屏蔽的有前途的替代导电填料[6,8,9]。目前,使用具有超高模量和强度、良好热学和电学性能的碳纳米管(CNTs)作为聚合物纳米复合材料的填料,制备的材料具有较低的填料负荷,并具有改善的电学和EMI屏蔽性能[10-15]。文献报道,聚合物纳米复合材料的机械强度、导电性或热性能以及电磁干扰屏蔽效能受到碳纳米管的纵横比、分散、加工方法、处理方法和载荷等不同因素的影响[16]。Li等[15]研究了填充不同宽高比SWCNTs的环氧/ SWCNTs纳米复合材料的电导率和EMI SE。据报道,具有15wt% SWCNTslong的环氧/SWCNT复合材料的最大EMI屏蔽效率(分别在10MHz和500MHz至1.5GHz范围内获得SE ~ 49dB和15-20dB)。在另一项研究中,Gupta等人[17]报道了聚对苯二甲酸三亚甲基酯(PTT)/MWCNT纳米复合材料的EMI屏蔽性能(在ku波段)。据报道,复合材料的电渗透在1wt%的MWCNT负荷下,SE为36-42dB,在10wt%的MWCNT负荷下。Bai等人[18]描述了纳米管长径比对纳米管的电学性能和机械强度的影响
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A Comparative Study of Multiwalled Carbon Nanotube Based Polystyrene and Toughened Polycarbonate Nanocomposites
The broad developments of electronic systems and telecommunications has led to a novel type of pollution i.e. electromagnetic interference (EMI). EMI has appeared as a major problem, which not only affecting the proper working of electronic devices but as well as causing harmful effects to the health of human beings [1,2]. Generally, mobile phone, radar, radio transceivers, microwave oven, and various electronic devices are the main causes of EMI [3,4]. The long time exposure of EM waves have also been recognized as strong cancer-causing agent [5]. Therefore, appropriate shield is required to reduce the effect of EM waves. Generally, electrically conductive or magnetic filler are used as a EMI shielding material, because these materials have capability to interact with coupled electric and magnetic fields of the incident EM waves [6,7]. Metals and metal loaded composites have been widely used as EMI shielding materials, but these materials have disadvantages such as high density, corrosion prone, inconvenient processing etc. which limits their practical applicability. As compare to the metals, carbon nanomaterials have appeared as promising alternative conductive filler for production of EMI shield [6,8,9]. Nowadays, the use of carbon nanotubes (CNTs), having ultra-high modulus and strength, good thermal and electrical properties, as filler in polymer nanocomposites prepare material with lower filler loadings having improved electrical and EMI shielding properties [10-15]. As reported in literature, mechanical strength, electrical conductivity or thermal properties and EMI shielding effectiveness of the polymer nanocomposites are affected by different factors such as the aspect ratio, dispersion, processing methods, treatment methods, and loading of CNTs [16]. Li et al. [15] studied the conductivity and EMI SE of epoxy/ SWCNT nanocomposites filled with SWCNTs having different aspect ratios. The maximum EMI shielding effectiveness has been reported for epoxy/SWCNT composites having 15wt% SWCNTslong (SE ∼49dB and 15-20dB obtained at 10MHz and in the 500MHz to 1.5GHz range respectively). In another study, Gupta et al. [17] reported EMI shielding properties (in Ku-band) of poly (trimethylene terephthalate) (PTT)/MWCNT nanocomposites. Electrical percolation of composites has been reported at 1wt% loading of MWCNT and SE of 36-42dB reported at 10wt% loading of MWCNT. Bai et al. [18] described the effect of nanotube aspect ratio on the electrical properties and mechanical strength of the
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