碳纳米材料对特种橡胶的改性

Trachevskyi Viacheslav, Kartel Mykola, S. Yurii, Zhuravskyi Serhii, W. Bo
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引用次数: 3

摘要

在大尺寸、低刚性的航空结构元件中,采用橡胶热防护涂层,该涂层在结构变形时不会坍塌。由于对材料的耐热性和抗冻性要求高,以及在辐射和真空条件下的稳定性要求高,橡胶在超音速飞机和航天器上的使用受到限制。因此,开发具有改进性能的新型橡胶是一个迫切需要解决的问题。多壁碳纳米管是已知的各向异性最强的材料之一,具有极高的杨氏模量值。碳纳米管的长径比大于103;这是它与其他纳米粒子的区别。近十年来,以碳纳米管为添加剂的新型复合材料得到了广泛的研究。复合材料的特点是具有极高的比强度性能、导电性和导热性。研究了多壁碳纳米管对丁腈基橡胶性能特性的影响,并对其进行了不同的预处理和引入方法。结果表明,在不同化学结构的弹性体中加入0.5 ~ 1.0 wt. %¢的碳纳米管,可提高弹性体的物理力学性能、耐磨性和耐老化性,显著提高弹性体的使用寿命。
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Modification of Specialty Rubbers by Carbon Nanomaterials
In the elements of aviation structures of large size and low rigidity rubber thermal protective coatings are used, which do not collapse when the structure is deformed. The use of rubber for supersonic aircraft and spacecraft is limited due to high requirements for heat and frost resistance of materials, as well as to their stability under the conditions of radiation and in a vacuum. Therefore, the development of new rubber with improved characteristics is an urgent problem. Multiwall carbon nanotubes are among the most anisotropic materials known and have extremely high values of Young's modulus. Carbon nanotube aspect ratio of length to diameter is more than 103; this distinguishes it from other nanoparticles. New composites with carbon nanotubes (CNTs) as additives were studied intensively during the last decade. Composites are characterized by extremely high specific strength properties, electrical and thermal conductivity. The effect of multiwalled carbon nanotubes on the performance characteristics of rubbers based on nitrile-butadiene was studied with various methods of their preliminary treatment and introduction into the composition of rubbers. It was shown that the introduction of 0.5-1.0 wt. % сarbon nanotubes into elastomers of different chemical structures leads to an increase in their physic mechanical characteristics, wear resistance and aging resistance, which significantly increases the service life of such products.
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