腐植酸分子印迹聚合物(MIPs)的合成与表征

T. Putri, M. Ali Zulfikar, D. Wahyuningrum, Iwan Syahjoko Saputra
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引用次数: 0

摘要

以甲基丙烯酸甲酯(MMA)为功能单体,乙二醇二甲基丙烯酸酯(EGDMA)为交联剂,过氧化苯甲酰(BPO)为引发剂,N,N-二甲基甲酰胺(DMF)为致孔溶剂,(HA)为模板剂,采用微波辅助有机合成(MAOS)法制备了MIPs。利用傅里叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、电子色散光谱仪(EDS)和紫外分光光度计对其进行表征,成功合成了MIPs。浸出后NIPs和MIPs的FTIR光谱中的其他官能团峰出现在2955 cm-1波长处,对应于C-H的伸缩振动1459 cm-1, 1160.06 cm-1波长处,对应于CH3和O-CH3的振动带。能谱分析表明,浸出后mip的元素组成为C、O和Si,质量分别为78.34、21.43和0.23%。紫外光谱显示,MIPs和NIPs的吸光度分别为0.36 nm和0.44 nm。
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Synthesis and Characterization of Molecularly Imprinted Polymers (MIPs) Using Humic Acid
MIPs was synthesized through microwave assisted organic synthesis (MAOS) method by using methyl methacrylate (MMA) as functional monomer, ethylene glycol dimethacrylate (EGDMA) as cross-linker, benzoyl peroxide (BPO) as initiator, N,N-dimethyl formamide (DMF) as porogen solvent, and (HA) as template. The MIPs was successfully synthesized according to the characterization using Fourier transform infrared (FTIR) spectroscopy, scanning electron microscope (SEM), electron dispersive spectrometer (EDS), and UV spectrophotometer. FTIR shows the other functional groups peaks in the FTIR spectra of NIPs and MIPs after leaching were appeared at the wavelength of 2955 cm-1 corresponded to stretching vibration of C-H of 1459 cm-1 and 1160.06 cm-1 corresponded to the vibration bands of CH3 and O-CH3. EDS shows the MIPs after leaching have the elemental compositions of C, O, and Si with a mass of 78.34, 21.43, and 0.23%. UV spectrum shows the MIPs and NIPs have absorbance values of 0.36 nm and 0.44 nm.
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