{"title":"利用混合阴离子策略设计d8结构的镍酸盐超导体","authors":"Naoya Kitamine, M. Ochi, K. Kuroki","doi":"10.1103/PHYSREVRESEARCH.2.042032","DOIUrl":null,"url":null,"abstract":"Inspired by a recently proposed superconducting mechanism for a new cuprate superconductor Ba$_2$CuO$_{3+\\delta}$, we theoretically design an unconventional nickelate superconductor with $d^8$ electron configuration. Our strategy is to enlarge the on-site energy difference between $3d_{x^2-y^2}$ and other $3d$ orbitals by adopting halogens or hydrogen as out-of-plane anions, so that the $3d$ bands other than $d_{x^-y^2}$ lie just below the Fermi level for the $d^8$ configuration, acting as incipient bands that enhance superconductivity. We also discuss a possible relevance of the present proposal to the recently discovered superconductor (Nd,Sr)NiO$_2$.","PeriodicalId":8514,"journal":{"name":"arXiv: Superconductivity","volume":"18 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":"{\"title\":\"Designing nickelate superconductors with \\nd8\\n configuration exploiting mixed-anion strategy\",\"authors\":\"Naoya Kitamine, M. Ochi, K. Kuroki\",\"doi\":\"10.1103/PHYSREVRESEARCH.2.042032\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Inspired by a recently proposed superconducting mechanism for a new cuprate superconductor Ba$_2$CuO$_{3+\\\\delta}$, we theoretically design an unconventional nickelate superconductor with $d^8$ electron configuration. Our strategy is to enlarge the on-site energy difference between $3d_{x^2-y^2}$ and other $3d$ orbitals by adopting halogens or hydrogen as out-of-plane anions, so that the $3d$ bands other than $d_{x^-y^2}$ lie just below the Fermi level for the $d^8$ configuration, acting as incipient bands that enhance superconductivity. We also discuss a possible relevance of the present proposal to the recently discovered superconductor (Nd,Sr)NiO$_2$.\",\"PeriodicalId\":8514,\"journal\":{\"name\":\"arXiv: Superconductivity\",\"volume\":\"18 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"arXiv: Superconductivity\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1103/PHYSREVRESEARCH.2.042032\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"arXiv: Superconductivity","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1103/PHYSREVRESEARCH.2.042032","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Designing nickelate superconductors with
d8
configuration exploiting mixed-anion strategy
Inspired by a recently proposed superconducting mechanism for a new cuprate superconductor Ba$_2$CuO$_{3+\delta}$, we theoretically design an unconventional nickelate superconductor with $d^8$ electron configuration. Our strategy is to enlarge the on-site energy difference between $3d_{x^2-y^2}$ and other $3d$ orbitals by adopting halogens or hydrogen as out-of-plane anions, so that the $3d$ bands other than $d_{x^-y^2}$ lie just below the Fermi level for the $d^8$ configuration, acting as incipient bands that enhance superconductivity. We also discuss a possible relevance of the present proposal to the recently discovered superconductor (Nd,Sr)NiO$_2$.