{"title":"高氯酸镍配合物与正丙胺的热裂解动力学","authors":"C. Singh, A. Singh","doi":"10.1155/2014/787306","DOIUrl":null,"url":null,"abstract":"Complex of nickel perchlorate with n-propylamine has been synthesised with molecular formula [Ni(n-pa)3(ClO4)(H2O)]ClO4. It has been characterised by elemental analysis, thermogravimetry, UV-VIS, and IR spectroscopic data. Thermal properties have been investigated by thermogravimetry (TG) in static air and by simultaneous thermogravimetry-derivative thermogravimetry-differential thermal analysis (TG-DTG-DTA) in flowing nitrogen atmosphere. Kinetics of thermolysis has been analysed applying model-fitting and model-free isoconversional method on isothermal TG data recorded at five different temperatures. To observe the response of complex towards fast heating, explosion delay time has been recorded at various temperatures and kinetics of explosion has been studied using these data.","PeriodicalId":13278,"journal":{"name":"Indian Journal of Materials Science","volume":"2 1","pages":"1-5"},"PeriodicalIF":0.0000,"publicationDate":"2014-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Kinetics of Thermolysis of Nickel(II) Perchlorate Complex with n-Propylamine\",\"authors\":\"C. Singh, A. Singh\",\"doi\":\"10.1155/2014/787306\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Complex of nickel perchlorate with n-propylamine has been synthesised with molecular formula [Ni(n-pa)3(ClO4)(H2O)]ClO4. It has been characterised by elemental analysis, thermogravimetry, UV-VIS, and IR spectroscopic data. Thermal properties have been investigated by thermogravimetry (TG) in static air and by simultaneous thermogravimetry-derivative thermogravimetry-differential thermal analysis (TG-DTG-DTA) in flowing nitrogen atmosphere. Kinetics of thermolysis has been analysed applying model-fitting and model-free isoconversional method on isothermal TG data recorded at five different temperatures. To observe the response of complex towards fast heating, explosion delay time has been recorded at various temperatures and kinetics of explosion has been studied using these data.\",\"PeriodicalId\":13278,\"journal\":{\"name\":\"Indian Journal of Materials Science\",\"volume\":\"2 1\",\"pages\":\"1-5\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-02-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Indian Journal of Materials Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2014/787306\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Indian Journal of Materials Science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2014/787306","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Kinetics of Thermolysis of Nickel(II) Perchlorate Complex with n-Propylamine
Complex of nickel perchlorate with n-propylamine has been synthesised with molecular formula [Ni(n-pa)3(ClO4)(H2O)]ClO4. It has been characterised by elemental analysis, thermogravimetry, UV-VIS, and IR spectroscopic data. Thermal properties have been investigated by thermogravimetry (TG) in static air and by simultaneous thermogravimetry-derivative thermogravimetry-differential thermal analysis (TG-DTG-DTA) in flowing nitrogen atmosphere. Kinetics of thermolysis has been analysed applying model-fitting and model-free isoconversional method on isothermal TG data recorded at five different temperatures. To observe the response of complex towards fast heating, explosion delay time has been recorded at various temperatures and kinetics of explosion has been studied using these data.
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