藻酸盐纳米颗粒/聚乙二醇二元共混物对水溶液中Cu(II)离子的吸附动力学研究

IF 0.5 4区 地球科学 Q4 Earth and Planetary Sciences Indian Journal of Geo-Marine Sciences Pub Date : 2022-05-01 DOI:10.56042/ijms.v51i05.65575
M. Saranya, T. Gomathi, S. Pavithra, A. Mubashirunnisa, P. Sudha
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引用次数: 1

摘要

海藻酸盐是最普遍的天然生物聚合物之一。目前的工作重点是创建Alg-Nps/PEG的二元混合物。PEG是一个很好的选择,因为它有许多独特的品质。聚合物的共混物混合了单独聚合物的特性。FTIR结果表明Alg-Nps/PEG二元共混物之间存在分子间氢键。形态学和横断面研究采用扫描电镜进行分析。利用Alg-Nps/PEG二元共混物,研究了影响Cu(II)离子吸附的各种参数,包括pH值、接触时间和吸附剂浓度。确定了伪一阶、伪二阶和粒子内的韦伯-莫里斯扩散参数。与拟一阶和拟一阶扩散模型相比,实验数据与拟二阶动力学模型拟合较好。
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Batch kinetic studies of adsorption of Cu(II) ions from aqueous solutions onto alginate nanoparticles/PEG binary blend
Among the most prevalent natural biopolymers is alginate. The current effort focuses on creating the binary blend of Alg-Nps/PEG. PEG is a great option because of its many distinctive qualities. Blends of polymers mix the characteristics of the separate polymers. FTIR results show intermolecular hydrogen bonding between Alg-Nps/PEG binary blend. Morphological and cross-sectional studies were analyzed using SEM. Various parameters impacting the Cu(II) ion adsorption, including pH, contact time, and adsorbent concentrations, have been examined in a batch adsorption method utilizing an Alg-Nps/PEG binary blend. Pseudo-first order, pseudo-second order, and intra particle Weber-Morris diffusion parameters have been determined. The experimental data fit the pseudo-second order kinetics model quite well when compared to the pseudo first order and intra-particular diffusion models.
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来源期刊
CiteScore
1.50
自引率
0.00%
发文量
0
审稿时长
1.7 months
期刊介绍: Started in 1972, this multi-disciplinary journal publishes full papers and short communications. The Indian Journal of Geo-Marine Sciences, issued monthly, is devoted to the publication of communications relating to various facets of research in (i) Marine sciences including marine engineering and marine pollution; (ii) Climate change & (iii) Geosciences i.e. geology, geography and geophysics. IJMS is a multidisciplinary journal in marine sciences and geosciences. Therefore, research and review papers and book reviews of general significance to marine sciences and geosciences which are written clearly and well organized will be given preference.
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