藻酸盐纳米颗粒/聚乙二醇二元共混物对水溶液中Cu(II)离子的吸附动力学研究

Pub Date : 2022-05-01 DOI:10.56042/ijms.v51i05.65575
M. Saranya, T. Gomathi, S. Pavithra, A. Mubashirunnisa, P. Sudha
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引用次数: 1

摘要

海藻酸盐是最普遍的天然生物聚合物之一。目前的工作重点是创建Alg-Nps/PEG的二元混合物。PEG是一个很好的选择,因为它有许多独特的品质。聚合物的共混物混合了单独聚合物的特性。FTIR结果表明Alg-Nps/PEG二元共混物之间存在分子间氢键。形态学和横断面研究采用扫描电镜进行分析。利用Alg-Nps/PEG二元共混物,研究了影响Cu(II)离子吸附的各种参数,包括pH值、接触时间和吸附剂浓度。确定了伪一阶、伪二阶和粒子内的韦伯-莫里斯扩散参数。与拟一阶和拟一阶扩散模型相比,实验数据与拟二阶动力学模型拟合较好。
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Batch kinetic studies of adsorption of Cu(II) ions from aqueous solutions onto alginate nanoparticles/PEG binary blend
Among the most prevalent natural biopolymers is alginate. The current effort focuses on creating the binary blend of Alg-Nps/PEG. PEG is a great option because of its many distinctive qualities. Blends of polymers mix the characteristics of the separate polymers. FTIR results show intermolecular hydrogen bonding between Alg-Nps/PEG binary blend. Morphological and cross-sectional studies were analyzed using SEM. Various parameters impacting the Cu(II) ion adsorption, including pH, contact time, and adsorbent concentrations, have been examined in a batch adsorption method utilizing an Alg-Nps/PEG binary blend. Pseudo-first order, pseudo-second order, and intra particle Weber-Morris diffusion parameters have been determined. The experimental data fit the pseudo-second order kinetics model quite well when compared to the pseudo first order and intra-particular diffusion models.
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