高温高压下脱水对粗面山岩电导率的影响

Lidong Dai, Keshi Hui, Wenqing Sun, Haiying Hu, Heping Li, Jian-jun Jiang
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摘要

采用YJ-3000t型多砧压力机和Solartron-1260型阻抗/增益相位分析仪,在0.5-2.0 GPa压力范围和773- 1323 K温度范围下,原位测量了粗灰岩的电导率。实验结果表明,粗面橄榄岩的电导率随温度升高而升高,随压力升高而降低。在一定温度范围内,电导率σ与温度T的关系符合Arrhenius方程。当温度升高到923 K时,粗面山岩的电导率急剧升高。结果表明,长径山岩在~923 K时开始脱水,脱水后生成具有高导电性矿相的磁铁矿。互连磁铁矿的相互生长是脱水后电导率提高2个数量级的原因。长径山岩样品脱水产物中磁铁矿的互连高导电性矿物相可以合理解释安第斯山脉下智利中南部俯冲带的高导电性异常。
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The Influence of Dehydration on the Electrical Conductivity of Trachyandesite at High Temperatures and High Pressures
The electrical conductivity of trachyteandesite was measured in situ under conditions of pressure range from 0.5-2.0 GPa and temperature range from 773-1,323 K using a YJ-3000t multi-anvil press and a Solartron-1260 Impedance/Gain-phase Analyzer. The experimental results indicate that the electrical conductivity of trachyteandesite increases with increasing temperature and decreases with a rise in pressure. The relationship between the electrical conductivity (σ) and temperature (T) conforms to the Arrhenius equation within a certain temperature range. When the temperature rises to 923 K, the electrical conductivity of trachyandesite abruptly increases. This result demonstrates that trachyandesite begins to dehydrate at ~923 K and produces magnetite with a high-conductivity mineral phase after dehydration. The intergrowth of interconnected magnetite is the cause for the ~2 orders of magnitude increase in the electrical conductivity after dehydration. The interconnected high-conductivity mineral phase of magnetite in the dehydration product of the trachyandesite sample can be used to reasonably explain the high-conductivity anomalies in the South-Central Chilean subduction zone beneath the Andes.
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