聚乙烯吡咯烷酮存在下钯、锰纳米粒子的合成及结构研究

N. Zeynalov, U. Mammadova, A. Isazade, N.T. Shikhverdiyeva, C. Seidova, H. Aslanova, N. Rahimli, K.J. Hasanova, E.H. Babayev
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摘要

聚n-乙烯基吡咯烷酮因其无毒、易溶于水和其他有机溶剂而被广泛应用于合成聚合物中。金属和非金属的复合化合物广泛应用于工业和医学的各个领域。本研究的目的是合成金属-聚合物配合物,以获得一种新型催化剂。先将聚n -乙烯吡咯烷酮溶解于水中,然后加入PdCl2盐重新混合。在溶液中加入还原剂,最后通过粘结剂使所得到的物质凝固。同样的过程也适用于MnCl2盐。通过各种研究方法(FTIR, XRD, SEM, UV-Vis)对得到的配合物进行了研究。从研究方法的结果来看,我们可以说,构建过程是成功的,金属纳米颗粒在聚合物表面和内部沉淀。所得的络合化合物拟用作催化剂
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SYNTHESIS AND STUDY OF THE STRUCTURE OF Pd AND Mn NANOPARTICLES IN THE PRESENCE OF POLYVINYLPYRROLIDONE
Poly-N-vinylpyrrolidone is widely used among synthetic polymers due to its non-toxicity and solubility in water and other organic solvents. Complex compounds with metals and non-metals find widespread application in various fields of industry and medicine. The purpose of this study is to synthesize metal-polymer complexes for obtaining a new type of catalyst. Poly-N-vinylpyrrolidone was first dissolved in water and then re-mixed with the addition of the PdCl2 salt. A reducing agent was added to the solution, and finally the resulting substance was established by means of a binder. The same process was typical for MnCl2 salt. Complexes obtained studied by various research methods (FTIR, XRD, SEM, UV-Vis). Proceeding from the results of the research methods, we can say that the construction process was successful and the metal nanoparticles settled on the surface and inside the polymer. The obtained complex compounds are intended to be used as catalysts
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