多组分可燃气体对CH4爆炸特性及自由基发射谱的影响

Luo Zhenmin, Wan Zijin, Su Bin, Li Kui, Shi-nong Jing
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引用次数: 1

摘要

为了研究多组分可燃气体对煤矿火区CH4爆炸特性的影响ꎬ,采用20 L多功能球形瓦斯爆炸装置进行了爆炸压力参数采集实验。然后通过数字示波器获得了CH4爆炸过程中关键自由基OH和CH2O的ꎬ发射光谱。最后ꎬ从宏观和微观两个方面分析了多组分可燃性气体对CH4爆炸特性的影响ꎬ并进行了关联和比较。研究表明,它们的影响因含氧量不同而表现出不同的特点。贫氧状态下多组分可燃气体含量的增加可以抑制CH4的爆炸。但随着氧含量的增加,其抑制作用逐渐减弱,直至达到富氧状态。关键自由基发射光谱的相对强度与相应的爆炸压力参数变化基本一致。虽然不同自由基参与反应过程的变化趋势相同ꎬ但受氧含量的影响程度不同ꎬ且CH2O∗ꎬ比OH∗ꎬ在反应过程中更容易受氧含量的影响。
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Influence of multi-component combustible gases on explosion characteristics and free radical emission spectrum of CH4
In order to investigate influence of multi ̄component combustible gases on explosion characteristics of CH4 in fire area of minesꎬ a 20 L multifunctional spherical gas explosion device was used for experiments to collect explosion pressure parameters. Thenꎬ emission spectra of key free radicals OH and CH2O of CH4 explosion were obtained through a digital oscilloscope. Finallyꎬ influence of multi ̄ 中 国 安 全 科 学 学 报 China Safety Science Journal 第30卷 2020年 component combustible gases on explosion characteristics of CH4 was analyzed from macro and micro aspectsꎬ and they were correlated and compared. The research shows that their influence indicates different characteristics due to different oxygen contents. An increase in multi ̄component combustible gas content under an oxygen ̄depleted state can inhibit explosion of CH4. But its inhibition effect gradually weakens as oxygen content increases until an oxygen ̄rich state is reached. Relative intensity of key radical emission spectra is basically consistent with corresponding changes of explosion pressure parameters. Although different radicals have the same change trend in participating in reaction processꎬ they are affected by oxygen content to different degreesꎬ and CH2O∗ꎬ compared with OH∗ꎬ is more susceptible to oxygen content during the process.
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来源期刊
CiteScore
1.30
自引率
0.00%
发文量
8733
期刊介绍: China Safety Science Journal is administered by China Association for Science and Technology and sponsored by China Occupational Safety and Health Association (formerly China Society of Science and Technology for Labor Protection). It was first published on January 20, 1991 and was approved for public distribution at home and abroad. China Safety Science Journal (CN 11-2865/X ISSN 1003-3033 CODEN ZAKXAM) is a monthly magazine, 12 issues a year, large 16 folo, the domestic price of each book is 40.00 yuan, the annual price is 480.00 yuan. Mailing code 82-454. Honors: Scopus database includes journals in the field of safety science of high-quality scientific journals classification catalog T1 level National Chinese core journals China Science and technology core journals CSCD journals The United States "Chemical Abstracts" search included the United States "Cambridge Scientific Abstracts: Materials Information" search included
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