用活性炭从水溶液中吸附食用色素诱惑红染料(e129)

S. Alkahtani, Samer S. Abu-Alrub, A. Mahmoud
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引用次数: 12

摘要

研究了活性炭对Allura红(E129)在水溶液中的吸附行为。仔细研究了影响吸附过程的各种因素,并对吸附条件进行了优化。降低活性炭的质量、溶液的pH值和离子强度以及提高温度,会增加E129在活性炭上的吸附。活性炭对紫红的吸附量较高。在最佳条件下,对E129染料的最大吸附量为72.85 mg/g。三种吸附模式;采用Langmuir、Freundlich和Temkin模型对E129的吸附进行了研究。对模型的参数kl、qm、R2、(n)分别为0.0222、72.85 mg/g、0.9057 ~ 0.9984、0.992。同时,通过拟一、二级动力学模型的测试,确定了E129染料在活性炭上吸附的最佳模型。结果表明,E129在活性炭上的吸附符合Freundlich等温线和准二级动力学模型。此外,热力学研究表明,E129染料在活性炭上的吸附是自发的。
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ADSORPTION OF FOOD COLORING ALLURA RED DYE (E129) FROM AQUEOUS SOLUTIONS USING ACTIVATED CARBON
The adsorption behavior of Allura red (E129) from aqueous solutions onto activated carbon was successfully investigated. All factors affecting the adsorption process were carefully studied and the conditions were optimized. Adsorption of E129 onto activated carbon was found to increase by decreasing the mass of activated carbon, pH and ionic strength of the solution and by increasing temperature. The adsorption capacity of the activated carbon for Allura red was relatively high. Under the optimum conditions, the maximum adsorption capacity for E129 dye was 72.85 mg/g. Three adsorption models; Langmuir, Freundlich and Temkin model were investigated regarding the adsorption of E129. The models’ parameters K L , qm, R2, (n) were determined and found to be 0.0222, 72.85 mg/g, 0.9057-0.9984, and 0.992, respectively. Also, pseudo first and second-order kinetic models were tested to determine the best-fit model to the adsorption of E129 dye onto activated carbon. The results showed that the adsorption of E129 onto activated carbon obeyed both the Freundlich isotherm and pseudo second-order kinetic models. Moreover, thermodynamic studies indicated that the adsorption of E129 dye onto the activated carbon was spontaneous.
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