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引用次数: 22

摘要

忽略Langmuir吸附速率方程中的解吸项,对不可逆速率方程进行积分,得到了间歇式吸附方程。积分方程与实验结果吻合较好,为从数据中确定参数q0和k1提供了一种方法。这些常数,即吸附容量和吸附速率常数,完全表征了该温度下的吸附体系。当两种类型的吸附同时进行时,这些间歇吸附参数与先前从柱吸附实验中得到的对应参数一致。
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Batch Adsorption From Solution
A batch adsorption equation was derived by integrating an irreversible rate equation obtained by neglecting the desorption term of the Langmuir adsorption-rate equation. The integrated equation was in reasonably good agreement with experiment and provided a means for determining from the data the parameters q0 and k1. These constants, namely, the adsorptive capacity and the adsorption rate constant, completely characterized the adsorption system at that temperature. Agreement was found between these batch adsorption parameters and their counterparts previously derived from column adsorption experiments when both types of adsorption were performed simultaneously.
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