用融雪的物理和化学特性测定大气污染

E. O. Markova, Yuliya P. Koryakina, Margarita A. Titova, Daria А. Baranova-Fedorova
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摘要

城市的环境状况是由环境各个组成部分的污染程度决定的。城市群地球化学异常多形成于土壤、积雪、底泥等污染沉积介质中。这项研究的目的是根据融雪的物理和化学特征,监测斯摩棱斯克和维亚济马不同地区的人为影响。之所以选择雪作为研究对象,是因为雪积累了许多进入大气的物质,随后会成为土壤覆盖层、地下水和地表水的二次污染源。该研究确定了感官参数(气味、颜色、浊度、熔体水中沉积物的存在)、化学参数(悬浮颗粒的数量、pH值、总硬度和矿化、有机物的数量)。测定了氯离子(Cl-)、硫酸盐离子(SO42-)、硝酸盐离子(NO3-)、亚硝酸盐离子(NO2-)、碳酸氢盐离子(HCO3-)和一些重金属离子(Pb2+、Cu2+、Fe3+)的存在。同时对所研究样品进行了豆瓣菜的生物适应证。斯摩棱斯克和维亚济马的空气污染水平较低。在一年中寒冷时期,对污染水平形成的最大贡献是悬浮物质,铁和锰化合物的浓度超过最大允许浓度。杂质的浓度取决于与大型工业物体、汽车和铁路物体的距离、卫生和技术条件以及领土的清洁制度。斯摩棱斯克和维亚济马的庭院是最干净的。雪污染的最大部分是由热电厂和交通运输提供的。在停车场、铁路轨道和热电厂附近采集的样本是最不利的。
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Determination of atmospheric air pollution by physical and chemical characteristics of snowmelt
The state of the environment in cities is determined by the degree of pollution of individual components of the environment. Geochemical anomalies in urban agglomerations are often formed in pollution depositing media such as soil, snow cover, bottom sediments. The purpose of the study is environmental monitoring of anthropogenic impact in different areas of Smolensk and Vyazma according to the physical and chemical characteristics of melted snow. Snow was chosen as the object of the study, because it accumulates many substances entering the atmosphere, and subsequently can become a source of secondary pollution of the soil cover, underground and surface waters. The study determined organoleptic parameters (smell, color, turbidity, the presence of sediment in melt water), chemical parameters (the number of suspended particles, pH, total rigidity and mineralization, the amount of organic substances).The presence of chloride ions (Cl-), sulfate ions (SO42-), nitrate ions (NO3-), nitrite ions (NO2-), bicarbonate ions (HCO3-) and ions of some heavy metals (Pb2+, Cu2+, Fe3+) have been determined. Bioindication of the studied samples on watercress has been carried out in parallel. A low level of air pollution in Smolensk and Vyazma has been established. The greatest contribution to the formation of the level of pollution in the cold period of the year is made by suspended substances, iron and manganese compounds in concentrations exceeding the maximum permissible concentration. The concentration of impurities depends on the distance from large industrial objects, automobile and railway objects, sanitary and technical condition and cleaning regime of the territory. The courtyard territories of Smolensk and Vyazma are the cleanest. The largest part of snow pollution is provided by the thermoelectric power stations and transport. Samples taken near car parks, railway tracks and near the thermoelectric power stations were the most unfavorable.
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