壳聚糖-碳纳米管凝胶的流变学研究

Murilo Álison Vigilato, M. Horn, V. Martins, A. Plepis
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引用次数: 8

摘要

壳聚糖/碳纳米管在组织再生中的应用。本文报道了壳聚糖与单壁碳纳米管(SWCN)混合制备凝胶的流变性能。利用流变学表征来了解凝胶的内部结构。壳聚糖/SWCN的频率试验表明,壳聚糖/SWCN凝胶具有弹性行为,且SWCN浓度的增加会增加其G′模量。凝胶的粘度值随着SWCN浓度的增加增加了10倍以上。温度结果表明,碳纳米管的加入改变了凝胶的行为。在所研究的温度范围内,用SWCN制备的凝胶的G′′均大于G′′。SWCN改变了壳聚糖的三维网络,得到了一种新的链排列方式。
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RHEOLOGICAL STUDY OF GELS BASED ON CHITOSAN AND CARBON NANOTUBES
Chitosan/carbon nanotubes associations have applications in tissue regeneration. This study reports on the rheological characterization of gels prepared by the mixture of chitosan and single-walled carbon nanotubes (SWCN). Rheological characterization was used to understand the internal structure of gels. Frequency tests of chitosan/SWCN showed that gels have elastic behavior, and also an increment in SWCN concentration increases G´ modulus. Gels had an increase in viscosity values of more than 10 times as a function of SWCN concentration. The addition of carbon nanotubes modified the behavior of gels as observed by temperature results. For all gels prepared with SWCN, G´ is higher than G´´ in the temperature range studied. SWCN changes the tridimensional network of chitosan and a new chain arrangement is obtained.
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