偏氰酸钠制备氧化钒纳米颗粒的化学合成

Majid Farahm, Jou, N. Abaeiyan
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引用次数: 54

摘要

纳米材料具有独特的物理性质,由于其高表面积和氧化还原活性,作为可充电离子电池和选择性气体传感器(如氨)的阴极,越来越受到人们的关注[1-3]。五氧化二钒纳米材料的生物活性取决于衍生物的类型、给药方式、剂量、治疗时间,以及个体和物种对所给化合物的特异性敏感性等因素[4]。V2O5纳米材料具有两性性质。钒与其氧化程度(vanadyl\vanadate离子)和化学形态(有机\无机配体)相关[5-7]。各种钒酸盐种类的存在取决于pH值和钒的总浓度。它们的出现可以用缩合平衡来解释;很明显,只有在非常稀的溶液中才会发现单体钒离子,而浓度的增加,特别是如果溶液是酸性的,会导致聚合[8-10]。钒氧体系(V2O5, VO2)是原型强相关材料,半个多世纪以来已被凝聚态和材料界广泛研究[11]。氧化钒是各种金属氧化物中较为知名的催化剂,围绕催化氧化展开了大量基础研究[12]。它们表现出金属-半导体转变,这意味着光学和电学性质的突然变化[13]。这就是为什么这种氧化物被用于热感测和开关。众所周知,五氧化二钒基材料显示出几种类型的显色效应,作为太阳能电池的窗口和智能窗口的透射率调制,在建筑、汽车和纳米医学中具有潜在的应用[14]。它表现出一种非典型的行为,因为它不能被精确地定义为阴极或阳极着色材料。V2O5表现出多色电致变色,可用于电致变色(EC)显示器、滤色器和其他光学器件[15]。
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Chemical Synthesis of Vanadium Oxide (V2O5) Nanoparticles Prepared by Sodium Metavanadate
Nano-materials have unique physical properties that have attracted more and more attention as a cathode in rechargeable ion batteries and selective gas sensors such as ammonia because of their high surface area and redox activity [1-3]. Biological activity of vanadium pentoxide nanomaterial depends on factors such as the type of the derivative, manner of its administration, dose, length of treatment, and also individualand species-specific sensitivity to the administered compound [4]. V2O5 nanomaterial is amphoteric in nature. Vanadium is correlated to its degree of oxidation (vanadyl\vanadate ion) and chemical form (organic\ inorganic ligand) [5-7]. The existence of the various vanadate species depends on the pH and on the total concentration of vanadium. Their occurrence can be accounted for condensation equilibrium; it is evident that only in very dilute solutions are monomeric vanadium ions found, and increases in concentration, particularly if the solution is acidic, lead to polymerization [8-10]. Vanadium oxygen systems (V2O5, VO2) are prototype stronglycorrelated materials that have been widely-studied by theoretical and experimental condensed-matter and materials community for more than half a century [11]. Vanadium oxide is a well-known catalyst among various metal oxides, and so many fundamental studies have been developed wide-spreadingly centering on catalytic oxidation [12]. They show metal-semiconductor transition, which implies an abrupt change in optical and electrical properties [13]. That is why this oxide is used in thermal sensing and switching. Vanadium pentoxide based materials are known to display several types of chromogenic effects, as a window for solar cells and for transmittance modulation in smart windows with potential applications in architecture, automotives and nanomedicine [14]. It shows an atypical behaviour because it cannot be defined exactly either as a cathodically or as anodically colouring material. V2O5 exhibit multi-colored electrochromism allowing the use in electrochromic (EC) displays color filters and other optical devices [15].
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