各种食用油制铜皂的表面活性和胶束特性

Q2 Pharmacology, Toxicology and Pharmaceutics Open Medicinal Chemistry Journal Pub Date : 2018-11-30 DOI:10.2174/1874842201805010119
A. Sharma, M. Saxena, Rashmi Sharma
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引用次数: 2

摘要

测定了从各种食用油中提取的铜表面活性剂在甲醇-苯溶剂中的摩尔体积、粘度、比粘度和流动性。利用所得结果计算了(CMC)、肥皂配合物与溶剂的相互作用以及表面活性剂分子链长对各参数的影响。用著名的穆利克方程和琼斯-多尔方程讨论了肥皂-肥皂和肥皂-甲醇-苯相互作用的结论。讨论了表面活性剂浓度对混合溶剂溶液粘度的影响。结果表明,在胶束形成后,溶质对溶剂分子的破坏作用在CMC以上比在CMC以下更为明显。生命信息在各种工业过程和生物应用中起着重要作用。
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Surface Active Properties and Micellar Features of Copper Soaps Derived from Various Edible Oils
The molar volume, viscosity, specific viscosity, and fluidity of copper surfactant derived from various edible oils in methanol -benzene solvent have been determined at a constant temperature 303 K.The results were used to calculate (CMC), soap complex-solvent interactions and the effect of chain length of the surfactant molecule on various parameters.The conclusions with regard to soap-soap and soap- methanol -benzene interaction have been discussed in terms of well-known Moulik’s and Jones- Dole equations. The effect of surfactant concentration on viscosity of the solution in solvent mixture has been discussed.The observations suggested that the structure breaking effect by the solute on the solvent molecules is more prominent above CMC as compared to below CMC after the formation of the micelles. The vital information plays an important role in various industrial process as well as biological applications.
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来源期刊
Open Medicinal Chemistry Journal
Open Medicinal Chemistry Journal Pharmacology, Toxicology and Pharmaceutics-Pharmaceutical Science
CiteScore
4.40
自引率
0.00%
发文量
4
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