韩国清州五松铁副产物科学分析的遗址特征

Da Yeon Jung, N. Cho
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引用次数: 0

摘要

通过对清州五松遗址出土的副产物进行科学分析,确定了遗址的特征,并同时对镇川松头里、镇川龟山里和清原莲济里遗址的副产物进行比较,探讨了遗址的区域特征。经熔炼的总铁和脱氧剂中,直接熔炼的总铁为33.16 ~ 59.01 wt%,脱氧剂为20.58 ~ 51.54 wt%,与此相对应。化合物分析结果表明,渣中的主要化合物为铁矾石、钨石、橄榄石。此外,显微组织分析结果证实了渣中存在铁矾石和钨钛石。其中,4个样品中有2个样品的CaO含量较高,XRD分析检测出了克氏石矿,拉曼微光谱分析也证实了克氏石矿。这是本次分析中使用的清州五松遗址矿渣的一个主要特征,估计原矿石中含有的成分已被洗脱。在局部接近的镇川松头里、镇川龟山里、清原莲济里,总铁和脱氧剂的总量相似,通过稀土元素的比较,估计原材料没有显著差异。结果表明,清州五松遗址采用含高CaO含量克氏石原矿直接熔炼制铁,4个遗址的炼铁工艺特征相似。
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Characteristics of Site from Scientific Analysis of Iron By-product Excavated from Osong in Cheongju, Korea
The characteristics of the sites were identified through scientific analysis of by-products excavated from Osong site in Cheongju, and regional characteristics were investigated by comparing the by-products of Jincheon Songdu-ri, Jincheon Gusan-ri, and Cheongwon Yeonje-ri site at the same time. In the total Fe and deoxidation agent by smelting, direct smelting total Fe is 33.16-59.01 wt%, and deoxidation agent is 20.58-51.54 wt%, and Osong sites correspond to this. The compound analysis result indicated that fayalite and wüstite, oliven are the main compounds in slag. Furthermore, the microstructure analysis result confirmed the presence of fayalite and wüstite in the slag. In particular, two of the four samples have high CaO content, and Kirschsteinite was detected as a result of XRD analysis, and Kirschsteinite was also confirmed in Raman micro-spectroscopy analysis. This is a major feature of the slag of Osong sites in Cheongju used in this analysis, and it is estimated that the ingredients contained in the original ore have been eluted. In the case of locally close Jincheon Songdu-ri, Jincheon Gusan-ri, and Cheongwon Yeonje-ri, the overall amount of total Fe and deoxidation agent were similar, and as a result of comparing rare earth elements, it is estimated that there is no significant difference in raw materials. Through these results, the Osong sites in Cheongju produced iron by direct smelting using raw ore containing Kirschsteinite with high CaO content, and similar iron-making process characteristics were confirmed in all four sites.
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来源期刊
CiteScore
1.70
自引率
37.50%
发文量
5
审稿时长
10 weeks
期刊介绍: The International Journal of Conservation Science (IJCS) is a high quality peer-reviewed journal devoted to the publication of original research papers in applied conservation science and its broad range of applications. IJCS it is an open access journal. All content is freely available without charge to any user or his/her institution. Users are allowed to read, download, copy, distribute, print, search, or link to the full texts of the articles in this journal without asking prior permission from the publisher or the author. The topics cover all disciplines and branches of modern scientific conservation, including different aspects on general conservation theory, scientific investigation of works of art, authentication, determination of conservation state, compatibility studies for preservation and restoration procedures and monitoring of interventions effectiveness, etiopathology of historic and natural monuments, studies on the mechanisms of deterioration and degradation for different materials as structural and ornamental elements, impact of the environmental factors or agents on monuments and ecosystems, obtaining and characterization of new materials and procedures for preservation and restoration, new methodologies for scientific investigation, cross-related problems concerning research applied to conservation science, biodiversity conservation. Review articles in selected areas are published from time to time.
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