两种潜在来源的石油到生物柴油——360度的比较研究

S. Nandi
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摘要

麻疯树油(JCO)和karanja油已被确定用于可再生能源即生物柴油的生产以及生物柴油的物理化学性质的潜力的比较研究。使用Novozyme 435酶(南极洲念珠菌)作为生物催化剂(8%)在两种情况下进行转化,酒精与油的摩尔比为5:1,搅拌强度为600转/分,在550C下搅拌8小时。在这些参数下,JCO的转化效率高于karanja油。从JCO和karanja油中获得的生物柴油根据物理化学性质进行分析,如比重、运动粘度、密度、热值、十六烷值、闪点、浊点和酸值。JCO生物柴油的比重、运动粘度、密度、热值和十六烷值均高于karanja生物柴油,而karanja生物柴油的闪点和浊点均高于JCO生物柴油。在成分分析方面,JCO生物柴油的甲酯含量为95.67%,karanja生物柴油的甲酯含量为92.57%。此外,甘油三酯(TG)、二甘油三酯(DG)和单甘油三酯(MG)含量分别为1.68%、1.08%、2.68%和1.89%、2.75%和3.69%。
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Oil to Biodiesel from Two Potential Sources – A 360 Degree Comparative Study
Jatropha curcas oil (JCO) and karanja oil have been identified for the comparative study of production of renewable energy sources i.e. biodiesel as well as physico-chemical properties of biodiesel for its potentiality. Enzyme Novozyme 435 (Candida antarctica) is used as biocatalyst (8%) for the conversion in both the cases with 5:1 molar ratio of alcohol to oil for 8 hours with mixing intensity of 600 rpm at 550C. JCO shows higher conversion efficiency at these parameters than karanja oil. Biodiesels obtained from JCO and karanja oil are analysed based on physico-chemical properties like specific gravity, kinematic viscosity, density, calorific value, cetane number, flash point, cloud point and acid number. With regard to specific gravity, kinematic viscosity, density, calorific value and cetane number, the JCO biodiesel shows higher values than karanja biodiesel whereas flash point and cloud point of karanja biodiesel are higher than JCO biodiesel. With respect to the compositional analysis, JCO biodiesel contains 95.67% methyl ester but karanja biodiesel contains 92.57% methyl ester. Apart from this, triglycerides (TG), diglycerides (DG) and monoglycerides (MG) content of JCO and karanja oil biodiesel are 1.68%, 1.08%, 2.68% and 1.89%, 2.75% and 3.69% respectively.
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