{"title":"镍离子与色氨酸络合物在过氧化氢异丙苯水溶液分解反应中均相催化剂的研究","authors":"G. S. Grigoryan","doi":"10.46991/pysu:b/2021.55.1.118","DOIUrl":null,"url":null,"abstract":"The formation of Ni2+:Tryptophan (Trp) 1:1 complex, which acts as a model catalyst for decomposition of cumene hydroperoxide (ROOH) in Ni2++Trp+ROOH+H2O system, has been confirmed via kinetic study in aqueous solution at pH>7. The kinetic expression of a single catalytic decomposition reaction of ROOH under the influence of [NiTrp]+ complex was brought out. The temperature dependence of the effective rate constant of ROOH decay (Keff=Kcat[Ni2+]0[Trp]0=const) in the temperature range from 323 to 343 K can be expressed by Arrhenius equation (Eeff is in kJ/mol): Keff=(1.87±0.02)·106exp[–(49.8±0.3)/RT], min –1.","PeriodicalId":20692,"journal":{"name":"Proceedings of the YSU B: Chemical and Biological Sciences","volume":"70 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"COMPLEX OF NICKEL (II) ION WITH TRYPTOPHAN AS A HOMOGENEOUS CATALYST IN THE DECOMPOSITION REACTION OF CUMENE HYDROPEROXIDE IN AQUEOUS SOLUTION\",\"authors\":\"G. S. Grigoryan\",\"doi\":\"10.46991/pysu:b/2021.55.1.118\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The formation of Ni2+:Tryptophan (Trp) 1:1 complex, which acts as a model catalyst for decomposition of cumene hydroperoxide (ROOH) in Ni2++Trp+ROOH+H2O system, has been confirmed via kinetic study in aqueous solution at pH>7. The kinetic expression of a single catalytic decomposition reaction of ROOH under the influence of [NiTrp]+ complex was brought out. The temperature dependence of the effective rate constant of ROOH decay (Keff=Kcat[Ni2+]0[Trp]0=const) in the temperature range from 323 to 343 K can be expressed by Arrhenius equation (Eeff is in kJ/mol): Keff=(1.87±0.02)·106exp[–(49.8±0.3)/RT], min –1.\",\"PeriodicalId\":20692,\"journal\":{\"name\":\"Proceedings of the YSU B: Chemical and Biological Sciences\",\"volume\":\"70 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of the YSU B: Chemical and Biological Sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.46991/pysu:b/2021.55.1.118\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the YSU B: Chemical and Biological Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.46991/pysu:b/2021.55.1.118","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
在pH>7的水溶液中，通过动力学研究证实了Ni2++Trp+ROOH+H2O体系中形成Ni2+:色氨酸(Trp) 1:1配合物，作为异丙苯过氧化氢(ROOH)分解的模型催化剂。给出了[NiTrp]+配合物作用下ROOH单催化分解反应的动力学表达式。在323 ~ 343 K范围内，ROOH衰变的有效速率常数(Keff=Kcat[Ni2+]0[Trp]0=const)与温度的关系可以用Arrhenius方程表示(Eeff单位为kJ/mol): Keff=(1.87±0.02)·106exp[-(49.8±0.3)/RT]， min - 1。
COMPLEX OF NICKEL (II) ION WITH TRYPTOPHAN AS A HOMOGENEOUS CATALYST IN THE DECOMPOSITION REACTION OF CUMENE HYDROPEROXIDE IN AQUEOUS SOLUTION
The formation of Ni2+:Tryptophan (Trp) 1:1 complex, which acts as a model catalyst for decomposition of cumene hydroperoxide (ROOH) in Ni2++Trp+ROOH+H2O system, has been confirmed via kinetic study in aqueous solution at pH>7. The kinetic expression of a single catalytic decomposition reaction of ROOH under the influence of [NiTrp]+ complex was brought out. The temperature dependence of the effective rate constant of ROOH decay (Keff=Kcat[Ni2+]0[Trp]0=const) in the temperature range from 323 to 343 K can be expressed by Arrhenius equation (Eeff is in kJ/mol): Keff=(1.87±0.02)·106exp[–(49.8±0.3)/RT], min –1.
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